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Arsenobetaine

 
Wikipedia: Arsenobetaine
Arsenobetaine
IUPAC name
Identifiers
CAS number [64436-13-1]
PubChem 47364
RTECS number CH9750000
SMILES
Properties
Molecular formula C5H11AsO2
Molar mass 178.06124 g/mol
Hazards
EU classification Toxic (T); Dangerous for the environment (N)
R-phrases R23/25 R50/53
S-phrases S20/21 S28 S45 S60 S61
Except where noted otherwise, data are given for
materials in their standard state
(at 25 °C, 100 kPa)

Infobox references

Arsenobetaine is an organoarsenic compound that is the main source of arsenic found in fish.[1] It is the arsenic analogue of trimethylglycine, commonly known as betaine. The biochemistry and its biosynthesis are similar to the biosynthesis of choline and betaine. The

Besides several other arsenic compounds, such as dimethylarsine and trimethylarsine, arsenobetaine is a common substance in the marine biological systems for arsenic detoxification.

It has been known since 1920 that marine fish contain organoarsenic compounds. In 1977 the structure of the main compound was discovered. [2]

References

  1. ^ Environmental Chemistry 2005 Volume 2 Issue 3
  2. ^ John S. Edmonds, Kevin A. Francesconi, Jack R. Cannon, Colin L. Raston, Brian W. Skelton and Allan H. White (1977). "Isolation, crystal structure and synthesis of arsenobetaine, the arsenical constituent of the western rock lobster panulirus longipes cygnus George". Tetrahedron Letters 18 (18): 1543–1546. doi:10.1016/S0040-4039(01)93098-9. 

Further reading


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