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arabinose

 
Dictionary: a·rab·i·nose   (ə-răb'ə-nōs', ăr'ə-bə-) pronunciation
n.
A crystalline pentose sugar, C5H10O5, obtained from plant polysaccharides such as gums and hemicelluloses.

[(GUM) ARAB(IC) + -IN + -OSE2.]


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Wikipedia: Arabinose
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Arabinose
IUPAC name
Other names Pectinose
Identifiers
CAS number 147-81-9,
10323-20-3 (D-isomer)
5328-37-0 (L-isomer)
PubChem 5460291
EC-number 205-699-8
Properties[1]
Molecular formula C5H10O5
Molar mass 150.13 g mol−1
Appearance colourless crystals (prisms or needles)
Density 1.585 g/cm3 (20 ºC)
Melting point

164–165 ºC

Solubility in water soluble
Related compounds
Related aldopentoses Ribose
Xylose
Lyxose
 Y(what is this?)  (verify)
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
Infobox references

Arabinose is an aldopentose – a monosaccharide containing five carbon atoms, and including an aldehyde (CHO) functional group.

The chemical structure of D-arabinofuranose

For biosynthetic reasons, most saccharides are almost always more abundant in nature as the "D"-form, or structurally analogous to D-glyceraldehyde.[note 1] However, L-arabinose is in fact more common than D-arabinose in nature and is found in nature as a component of biopolymers such as hemicellulose and pectin. The L-arabinose operon is a very important operon in molecular biology and bioengineering.

A classic method for the organic synthesis of arabinose from glucose is the Wohl degradation.[2]

Notes

  1. ^ For sugars, the D/L nomenclature does not refer to the molecule's optical rotation properties but to its structural analogy to glyceraldehyde.

References

  1. ^ Weast, Robert C., ed. (1981), CRC Handbook of Chemistry and Physics (62nd ed.), Boca Raton, FL: CRC Press, p. C-110, ISBN 0-8493-0462-8 .
  2. ^ Braun, Géza (1940), "D-Arabinose", Org. Synth. 20: 14, http://www.orgsyn.org/orgsyn/orgsyn/prepContent.asp?prep=CV3P0101 ; Coll. Vol. 3: 101 .

 
 

 

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Dictionary. The American Heritage® Dictionary of the English Language, Fourth Edition Copyright © 2007, 2000 by Houghton Mifflin Company. Updated in 2009. Published by Houghton Mifflin Company. All rights reserved.  Read more
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