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Well they are both used in the Autonomic system and Somatic system. Acetylcholine is the neurochemical which stimulates muscles. (I assume you mean NA=Sodium?) when the Acetylcholine binds with the muscle it causes sodium to diffuse in to the cell and potassium to diffuse out, causing depolarization and an Action Potential to be formed. This ultimately causes the muscle to move.

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Q: Autonomic nervous system uses ACh and NA as chemical neurotransmitters?
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