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with HCl the reaction is endothermic and homolysis of HCl does not occur as the effect follows free radical mechanism.

The homolysis of HI occurs but the i radical forms iodine molecule and also it's activation energy is high.

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Q: Why peroxide effect is not observed in HCl and HF and HCl?
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HF HCl boiling temperature?

Boiling point of HCl: -85,1 0C. Boiling point of HF: 19,5 0C.


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HF has a higher [OH-] than a solution of 1.0 M HCl.


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