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Radiator caps are pressure relief valves. They are rated at "pounds per square inch" and are designed to release some pressure from the radiator if it gets too high. If an engine overheats it can boil the coolant and this will cause the radiator cap to let out steam. Radiator caps DO lose their ability to regulate pressure and can release too soon. If the engine has not overheated, have the radiator cap tested and replaced as necessary.

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Q: Why would steam be coming out from the radiator cap?
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