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the Goodyear brothers invented vulcanization of rubber.

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the Goodyear brothers invented vulcanization of rubber.

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vulcanization process of rubber and vulcanization process of rubber.

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Goodyear says 1839.

http://en.wikipedia.org/wiki/Vulcanization#Overview_and_history

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1839

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Ageing is what happens over time to the material; vulcanization is a process whereby something hardens.

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