A carbogen, also known as a C-H bond, is a single bond between carbon and hydrogen atoms, most commonly found in organic compounds [1]. Carbon-hydrogen bonds have a bond length of 1.09 Å (1.09 × 10-10 m) and a bond energy of 413 kJ/mol. Using Pauling's scale--C (2.5) and H (2.1)--the electronegativity difference between these two atoms is 0.4. The bond type this electronegativity difference determines is generally regarded as being non-polar.
Compound classes consisting solely of C-H bonds and C-C bonds are alkanes, alkenes, alkynes and arene compounds.
The C-H bond in general is very unreactive; in structural formulas of molecules, the hydrogen atoms are in fact omitted. In several compound classes, collectively called carbon acids, the C-H bond can be sufficiently acidic for proton removal. Unactivated C-H bonds participate in radical substitution. Another reaction type involving C-H bonds is so-called C-H bond activation mediated by metals and carbene C-H insertion.
See also
| CH | He | |||||||||||||||||
| CLi | CBe | CB | CC | CN | CO | CF | Ne | |||||||||||
| CNa | CMg | CAl | CSi | CP | CS | CCl | Ar | |||||||||||
| CK | CCa | CSc | CTi | CV | CCr | CMn | CFe | CCo | CNi | CCu | CZn | CGa | CGe | CAs | CSe | CBr | CKr | |
| CRb | CSr | CY | CZr | CNb | CMo | CTc | CRu | CRh | CPd | CAg | CCd | CIn | CSn | CSb | CTe | CI | CXe | |
| CCs | CBa | CHf | CTa | CW | CRe | COs | CIr | CPt | CAu | CHg | CTl | CPb | CBi | CPo | CAt | Rn | ||
| Fr | Ra | Rf | Db | Sg | Bh | Hs | Mt | Ds | Rg | Uub | Uut | Uuq | Uup | Uuh | Uus | Uuo | ||
| ↓ | ||||||||||||||||||
| La | CCe | Pr | Nd | Pm | Sm | Eu | Gd | Tb | Dy | Ho | Er | Tm | Yb | Lu | ||||
| Ac | Th | Pa | CU | Np | Pu | Am | Cm | Bk | Cf | Es | Fm | Md | No | Lr | ||||
| Core organic chemistry | Many uses in chemistry. |
| Academic research, but no widespread use | Bond unknown / not assessed. |
References
- ^ March, Jerry (1985), Advanced Organic Chemistry: Reactions, Mechanisms, and Structure (3rd ed.), New York: Wiley, ISBN 0-471-85472-7
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