In geology say, a gross sample would be a representative sample of the whole rock. A lab sample would be a fraction of that, refined such that measurements are able to be made on a single mineral.
for example, a piece of basalt would be a convenient field (gross) sample, from which say, mica is extracted after grinding and separation, to enable the 'date' of the basalt to be determined.
Similar concepts would apply in other fields, such as biology, botany, water sampling and so on.