| Picture | Name | Notes | Period |
 |
José Gregorio Argomedo Montero | 1823-1825 | |
| Juan de Dios Vial del Río | 1825-1850 | ||
 |
Manuel Montt Torres | 1850-1851 | |
| Ramón Luis Yrarrázaval Alcalde | 1851-1855 | ||
| Manuel Cerda y Concha | 1855-1861 | ||
|
Manuel Montt Torres | 1861-1880 | |
| José Miguel Barriga Castro | 1880-1881 | ||
| Alejandro Reyes Cotapos | 1882 | ||
| Alvaro Covarrubias Ortúzar | 1883 | ||
| José de Bernales Urmeneta | 1884 | ||
 |
Belisario Prats Pérez | 1885 | |
| José Fructuoso Cousiño Fernández | 1886 | ||
| Alvaro Covarrubias Ortúzar | 1887 | ||
| José de Bernales Urmeneta | 1888 | ||
| José Fructuoso Cousiño Fernández | 1889-1890 | ||
| José Vicente Ábalos Valderrama | 1891 | ||
| Gregorio Amunátegui Aldunate | 1891-1892 | ||
| José María Barceló Carvallo | 1893 | ||
| Carlos Risopatrón Escudero | 1894 | ||
| José Alfonso Cavada | 1895 | ||
| Andrés Sanhueza Araneda | 1896 | ||
| Máximo Flores Zamudio | 1897 | ||
| Leopoldo Urrutia Anguita | 1898 | ||
| José Gabriel Palma Guzmán | 1899 | ||
| Carlos Eugenio Casanueva Ramos | 1900 | ||
| Ramón Huidobro Luco | 1901 | ||
| José Alfonso Cavada | 1902 | ||
| Galvarino Gallardo Font | 1903 | ||
| Gabriel Gaete Ríos | 1904 | ||
| Vicente Aguirre Palma | 1905 | ||
| Leoncio Rodríguez Rodríguez | 1906 | ||
| Carlos Varas Herrera | 1907 | ||
| Leopoldo Urrutia Anguita | 1908 | ||
| José Gabriel Palma Guzmán | 1909 | ||
| Enrique Foster Recabarren | 1910 | ||
| José de Bernales Mancheño | 1911 | ||
| Luis Vial Ugarte | 1912 | ||
| Galvarino Gallardo Font | 1913 | ||
| Gabriel Gaete Ríos | 1914 | ||
| Eleazar Donoso Vildosola | 1915 | ||
| Eduardo Castillo Vicuña | 1916 | ||
| Carlos Varas Herrera | 1917 | ||
| Luis Silva Silva | 1918 | ||
| Gabriel Gaete Ríos | 1919-1922 | ||
| Braulio Moreno Velásquez | 1922-1925 | ||
 |
Javier Angel Figueroa Larraín | 1925-1927 | |
| Felipe Ricardo Anguita Acuña | 1927 | ||
| Gustavo Sepúlveda Lagos | 1927-1929 | ||
| Dagoberto Lagos Pantoja | 1929-1931 | ||
|
Javier Angel Figueroa Larraín | 1931-1932 | |
| Abraham Oyanedel Urrutia | 1932-1934 | ||
| Humberto Trucco Franzani | 1934-1937 | ||
| Romilio Burgos Melo | 1938-1940 | ||
| Carlos Alberto Novoa Sepúlveda | 1940-1943 | ||
| Humberto Trucco Franzani | 1944-1950 | ||
| Gregorio Schepeler Pinochet | 1951-1954 | ||
| Humberto Bianchi Valenzuela | 1954-1957 | ||
| Miguel Aylwin Gajardo | 1957-1960 | ||
| Rafael Fontecilla Riquelma | 1960-1963 | ||
| Pedro Silva Fernández | 1963-1966 | ||
| Osvaldo Illanes Benítez | 1966-1969 | ||
| Ramiro Méndez Brañas | 1962-1972 | ||
| Enrique Urrutia Manzano | 1972-1975 | ||
| José María Eyzaguirre Echeverría | 1975-1978 | ||
| Israel Bórquez Montero | 1978-1983 | ||
| Rafael Retamal López | 1983-1988 | ||
| Luis Maldonado Boggiano | 1988-1991 | ||
| Enrique Correa Labra | 1991-1993 | ||
| Marcos Aburto Ochoa | 1993-1995 | ||
| Servando Jordán López | 1996-1997 | ||
| Roberto Dávila Díaz | 1998-1999 | ||
| Hernán Álvarez García | 2000-2001 | ||
| Mario Garrido Montt | 2002-2003 | ||
| Marcos Libedinsky Tschorne | 2004-2005 | ||
| Enrique Tapia Witting | 2006-January 6, 2008 | ||
| Urbano Marín Vallejo | January 6, 2008-incumbent |
See also
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