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Lithium iodide

 
Sci-Tech Dictionary: lithium iodide
(′lith·ē·əm ′ī·ə′dīd)

(inorganic chemistry) LiI; LiI·3H2O White, water- and alcohol-soluble crystals; LiI melts at 446°C; LiI·3H2O loses water at 72°C; used in medicine, photography, and mineral waters.


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Lithium iodide
Lithium iodide
Identifiers
CAS number 10377-51-2 Yes check.svgY,
17023-24-4 (monohydrate)
17023-25-5 (dihydrate)
7790-22-9 (trihydrate)
PubChem 66321
Properties
Molecular formula LiI
Molar mass 133.85 g/mol
Appearance White crystalline solid
Density 4.076 g/cm3 (anhydrous)
3.494 g/cm3 (trihydrate)
Melting point

459 °C

Boiling point

1171 °C

Solubility in water 151 g/100 mL (25 °C)
433 g/100 mL (100 °C) [1]
Solubility in methanol 343 g/100 mL (20 °C)
Solubility in acetone 42.6 g/100 mL (18 °C)
Refractive index (nD) 1.955
Thermochemistry
Std enthalpy of
formation
ΔfHo298
-2.02 kJ/g
Specific heat capacity, C 0.381 J/g K
Hazards
MSDS External MSDS
EU Index Not listed
Flash point Non-flammable
Related compounds
Other anions Lithium fluoride
Lithium chloride
Lithium bromide.
Other cations Sodium iodide
Potassium iodide
Rubidium iodide
Caesium iodide
 Yes check.svgY (what is this?)  (verify)
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
Infobox references

Lithium iodide, or LiI, is a compound of lithium and iodine. When exposed to air, it becomes yellow in color, due to the oxidation of iodide to iodine.[2]

Contents

Applications

Lithium iodide is used as an electrolyte for high temperature batteries. It is also used for long life batteries as required, for example, by artificial pacemakers. The solid is used as a phosphor for neutron detection.[3] The chemical formula for Lithium iodide is LiI.

See also

References

  1. ^ Pradyot Patnaik. Handbook of Inorganic Chemicals. McGraw-Hill, 2002, ISBN 0070494398
  2. ^ "A PDF file from ESPICorp Inc., a supplier of lithium iodide" (PDF). http://www.espimetals.com/msds's/lithiumiodide.pdf. Retrieved 2005-09-16. 
  3. ^ Some lithium iodide phosphors for slow neutron detection, K. P. Nicholson et al. Br. J. Appl. Phys. 6 104-106 (1955) doi:10.1088/0508-3443/6/3/311

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