Molecular beams

(physics) A beam of neutral molecules whose directions of motion lie within a very small solid angle.

Well-directed streams of atoms or molecules in vacuum. Utilization ofmolecular beams is a cornerstone technique in the investigation of molecularstructure and interactions. Molecular beams are usually formed at sufficientlylow particle density for the interaction of one beam molecule with another tobe negligible. This ensemble of truly isolated molecules is available for thespectroscopic study of molecular energy levels using photon probes from theradio-frequency to optical portions of the electromagnetic spectrum. Some ofthe best-determined fundamental knowledge of physics comes from spectroscopicmolecular-beam experiments. Beyond this, beams can be applied as probes of themultifaceted nature of gases, plasmas, surfaces, and even the structure ofsolids. An application intermediate in complexity is the study of molecularinteractions by means of two colliding beams, where one might be a beam ofcharged particles such as ions or electrons. See also Scattering experiments (atoms and molecules).

One simple means of forming a beam is to permit gas from an enclosed chamberto escape through a small orifice into a second chamber maintained at highvacuum by means of large pumps (illus. a). A useful number of molecules passes forward along thehorizontal axis of the apparatus. A well-collimated beam is then formed byrequiring that those molecules entering the test chamber where an experiment isto be performed pass not only through the orifice but also through a secondsmall hole separating the collimating and test chambers.

Schematic diagrams of systems for producing molecular beams.(a) Conventional oven-beam system. (b) Charge-exchange beamsystem.

If higher velocities are desired, a charge-exchange beam system can be used. In this scheme (illus. b), ions are produced by some ionizing process such as electron impact on atoms within a gas discharge. Since the ions are electrically charged, they can be accelerated to the desired velocity and focused into a beam using electric or magnetic fields. The last step in neutrally charged beam formation is to pass the ions through a neutralizing gas where electrons from the gas molecules are transferred to the beam ions in charge-exchange molecular collisions. See also Ion sources.

Much of molecular spectroscopy involves the absorption or emission of light by molecules in a gas sample. The frequency of the light photon is proportional to the separation of molecular energy levels involved in the spectroscopic transition. However, the molecule density in typical gas samples is so high that the energy levels are slightly altered by collisions between molecules, with the transition frequency no longer characteristic of the free molecule. The use of low-density molecular beams with their sensitive detection techniques can reduce this collision alteration problem, with the result that atomic properties can be measured to accuracies of parts per million or even better. If the very simplest atoms or molecules are employed, the basic electromagnetic interactions holding the component electrons and nuclei together can be precisely studied. This is of great importance to fundamental physics, since theoretical understanding of electromagnetic interactions through quantum electrodynamics represents the most successful application of quantum field theory to elementary particle physics problems. See also Quantum electrodynamics; Quantum field theory.

The development of tunable, strong laser sources of single-frequency light beams has added another dimension to molecular-beam experiments. With laser radiation resonantly tuned to excite a molecule from its normal ground state to one of its infinite number of vibrationally, rotationally, and electronically excited states, the number of possible studies and applications of excited molecular beams becomes enormous. See also Laser spectroscopy; Molecular structure and spectra; Nuclear structure.