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niter

 
Dictionary: ni·ter   ('tər) pronunciation
n.
A white, gray, or colorless mineral of potassium nitrate, KNO3, used in making gunpowder. Also called saltpeter.

[Middle English nitre, sodium carbonate, natron, from Old French, from Latin nitrum, from Greek nitron, from Egyptian nṯr.]


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A potassium nitrate mineral with chemical composition KNO3. Niter crystallizes in the orthorhombic system, generally in thin crusts and delicate acicular crystals; it occurs in massive, granular, or earthy forms. It is brittle; hardness is 2 on Mohs scale; specific gravity is 2.109. The luster is vitreous, and the color and streak are colorless to white. See also Nitrate minerals.

Niter is commonly found, usually in small amounts, as a surface efflorescence in arid regions and in caves and other sheltered places. Niter occurs associated with soda niter in the desert regions of northern Chile, and in similar occurrences in Italy, Egypt, Russia, the western United States, and elsewhere.



Brit. nitre

n. another term for potassium nitrate.

See the Introduction, Abbreviations and Pronunciation for further details.


KNO
Orthorhombic -- Rhombic bipyramidal

Environment

Cavern walls, as an efflorescence. Also in dry soils in the floor of bat caves but recovered only by dissolving in water, titrating, and recrystallizing.

Crystal description

Occurs as thin crusts and as silky short fibers on rock surfaces, cavern walls, etc. Never in well-formed crystals (but crystals easily produced in the laboratory; hence, data on cleavage, fracture, and tenacity are available).

Physical properties

White. Luster glassy; hardness 2; specific gravity 2.1; cleavage good. Fragile, slightly sectile.

Composition

Potassium nitrate--"saltpeter" (46.5% K 2 O, 53.5% N 2 O 5 ).

Tests

Like soda niter, but burns and explodes on hot coals, with violet flame.

Distinguishing characteristics

Behavior on coals distinguishes it from other salts, and the violet flame characterizes it as a potassium mineral.

Occurrence

Niter is found only as an efflorescence that forms on surfaces protected from rain, as in caves and along cliffs, from solutions percolating down through the rocks. Probably of organic origin. Rarer than soda niter but sometimes useful as a fertilizer, for which caves have been mined. Found in the dirt floor of caves in Kentucky and Tennessee, and sometimes in efflorescences along the limestone cliffs.



Wikipedia: Niter
Top
Niter
General
Category Nitrate minerals
Chemical formula KNO3
Strunz classification 05.NA.10
Dana classification 18.1.2.1
Crystal symmetry 2/m 2/m 2/m
Identification
Color white
Crystal habit encrustations
Crystal system orthorhombic
Cleavage very good on {001}; good on {010}
Fracture brittle
Mohs scale hardness 2
Luster vitreous
Streak white
Diaphaneity transparent
Specific gravity 2.10 (calc.)
Refractive index nα = 1.332
nβ = 1.504
nγ = 1.504
Solubility soluble
References [1][2][3]

Niter (US) or nitre (UK) is the mineral form of potassium nitrate, KNO3, also known as saltpeter (US) or saltpetre (UK). Historically, the term "nitre" – cognate with "natrium", a Latin word for sodium – has been very vaguely defined, and it has been applied to a variety of other minerals and chemical compounds, including sodium nitrate (also "soda nitre" or "cubic nitre"), sodium carbonate and potassium carbonate. This article is about the mineral form of potassium nitrate, which is the usual modern meaning.

Because of its ready solubility in water, niter is most often found in arid environments. A major source is the Atacama desert in Chile.Potassium and other nitrates are of great importance for use in fertilisers, and, historically, gunpowder. Much of the world's demand is now met by synthetically produced nitrates, though the natural mineral is still mined and is still of significant commercial value: as of 2007, Chilean potassium nitrate was reportedly trading at around USD 1000 per tonne.[4]

Contents

Description

Niter is a colourless to white mineral crystallizing in the orthorhombic crystal system. It usually is found as massive encrustations and effervescent growths on cavern walls and ceilings where solutions containing alkali potassium and nitrate seep into the openings. It occasionally occurs as prismatic acicular crystal groups, and individual crystals commonly show twinning.

History

Niter has been known since ancient times. The name is from Hebrew néter, for salt-derived ashes. It may have been used as, or in conjunction with soap, as implied by Jeremiah 2:22, "For though thou wash me with nitre, and take thee much sope…" However, it is not certain which substance (or substances) the Biblical "neter" refers to, with some suggesting sodium carbonate. A term (ἀφρόνιτρον) which translates as "foam of nitre" was a regular purchase in a fourth-century AD series of financial accounts, and since it was expressed as being "for the baths" was probably used as soap [5].

In literature, Edgar Allan Poe invokes the use of nitre in the short story "The Cask of Amontillado" (1846), in which the main character, Montresor, describes the mineral deposits lining the walls of the underground catacombs, where he lures Fortunato to his death.

See also

References

  1. ^ Template:WebMineral-ref.
  2. ^ Template:MinDat-ref.
  3. ^ Adiwidjaja, G.; Pohl, D. (2003), "Superstructure of α-phase potassium nitrate", Acta Crystallogr., Sect. C: Cryst. Struct. Commun. 59: 1139–40 .
  4. ^ Atacama Major Expansion Into Nitrate Production
  5. ^ More conventional soap also appears in the accounts but was more expensive: John Matthews, The Journey of Theophanes, Yale UP 2006

External links



 
 

 

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US Military Dictionary. The Oxford Essential Dictionary of the U.S. Military. Copyright © 2001, 2002 by Oxford University Press, Inc. All rights reserved.  Read more
Rock & Mineral Guide. Peterson Field Guide to Rocks and Minerals, by Frederick H. Pough. Copyright © 1998 by Houghton Mifflin Company. Published by Houghton Mifflin Company. All rights reserved.  Read more
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