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Pyrotechnic colorant

 
Wikipedia: Pyrotechnic colorant

A Pyrotechnic colorant is a chemical compound which causes a flame to burn with a particular color. These are used to create the colors in fireworks. Some common examples are:

Colour Compound name Chemical formula Notes
Red Strontium nitrate SrNO3 Common. Used with chlorine donors. Excellent red, especially with metal fuels. Used in many compositions including road flares.
Red Strontium carbonate SrCO3 Common. Produces good red. Slows burning of compositions. Fire retardant in gunpowders. Inexpensive, non-hygroscopic, neutralizes acids.
Red Strontium sulfate SrSO4 High-temperature oxidizer. Used in strobe mixtures and some metal-based red compositions.
Orange Calcium chloride CaCl2
Orange Calcium sulfate CaSO4 High-temperature oxidizer. Excellent orange source in strobe compositions.
Orange Hydrated calcium sulfate CaSO4(H2O)x*
Gold/Yellow Charcoal powder C
Gold/Yellow Iron powder with [[carbon]oxygen based carbon OC12] Fe+C
Gold/Yellow Sodium nitrate NaNO3
Gold/Yellow Cryolite Na3AlF6 One of few sodium salts that is nonhygroscopic and insoluble in water.
Green Barium chloride BaCl2
Green Barium chlorate BaClO3 Sensitive to shock and friction. Oxidizer.
Green Barium carbonate BaCO3
Green Barium nitrate Ba(NO3)2 Not too strong effect. With chlorine donors yields green color, without chlorine burns white. In green compositions usually used with perchlorates.
Green Barium oxalate BaC2O4
Blue Copper(I) chloride CuCl Richest blue flame. Almost insoluble in water.
Blue Copper(I) oxide Cu2O
Blue Copper(II) oxide CuO Used with chlorine donors. Excellent in composite stars.
Blue Copper carbonate CuCO3 Best when used with ammonium perchlorate.
Blue Copper oxychloride 3CuO.CuCl2 Used in cheap compositions. Not common anymore due to need for mercury(II) chloride to bring out the color.
Blue Paris Green Cu(C2H3O2)2.3Cu(AsO2)2 Toxic. With potassium perchlorate produces the best blue colors.
Blue Copper metal Cu Rarely used, other compounds are easier to work with.
Purple Combination of red and blue compounds Sr+Cu
Purple Rubidium compounds Rb rarely used
Silver/White Aluminium powder Al
Silver/White Magnesium powder Mg
Silver/White Titanium powder Ti
Silver/White Antimony (III) sulfide Sb2S3
Infrared Caesium nitrate CsNO3 two powerful spectral lines at 852.113 nm and 894.347 nm
Infrared Rubidium nitrate RbNO3

The * indicates that the compound will burn orange where x=0,2,3,5.

The color blue is notoriously difficult to produce in fireworks, as the copper compounds need to be heated at a specific temperature for the optimal shade of blue to be produced. Thus, a deep, rich blue is usually viewed as the mark of an experienced fireworks maker.

In many cases, chlorine donors have to be added in order to achieve sufficiently deep colors.

Care should be taken to avoid formation of solid particles, whether metal oxides or carbon; incandescent solid particles emit black body radiation that causes "washing out" of the colors.

Despite the wide numbers of metal ion donors, they serve to form only a few atomic and molecular species that are useful as light emitters:

Colour Emitter Wavelengths Notes
Yellow Sodium (D-line) 589 nm very strong, overpowers other colors, avoid contamination
Orange CaCl (molecular bands) most intense: 591-599 nm and 603-608 nm, and others
Red SrCl (molecular bands) a: 617-623 nm
b: 627-635 nm
c: 640-646 nm
Red SrOH(?) (molecular bands) 600-613 nm
Green BaCl (molecular bands) a: 511-515 nm
b: 524-528 nm
d: 530-533 nm
Lines of BaOH and BaO often present, emitting in yellow and yellowish-green
Blue CuCl (molecular bands) several intense bands between 403-456 nm, less intense at 460-530 nm

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