Samarium–cobalt magnet

A samarium-cobalt magnet, one of the two types of rare earth magnet, is a strong permanent magnet made of an alloy of samarium and cobalt. They were developed in the early 1970s. They are generally the second-strongest type of magnet made, less strong than neodymium magnets, but have higher temperature ratings. They are expensive, brittle, and prone to cracking and chipping. Samarium-cobalt magnets have maximum energy products (BH_max) that range from 16 megagauss-oersteds (MGOe) to 32 MGOe; their theoretical limit is 34 MGOe. They are available in two "series", namely Series 1:5 and Series 2:17.

Series 1:5

These samarium-cobalt magnet alloys (generally written as SmCo₅, or SmCo Series 1:5) have one atom of rare earth samarium and five atoms of cobalt. By weight this magnet alloy will typically contain 36% samarium with the balance cobalt. The energy products of these samarium cobalt alloys range from 16 MGOe to 25 MGOe. These Samarium Cobalt magnets generally have a reversible temperature coefficient of -0.05%/°C. Saturation magnetization can be achieved with a moderate magnetizing field. This series of magnet is easier to calibrate to a specific magnetic field than the SmCo 2:17 series magnets.

In the presence of a moderately strong magnetic field, unmagnetized magnets of this series will try to align its orientation axis to the magnetic field. Unmagnetized magnets of this series when exposed to moderately strong fields will become slightly magnetized. This can be an issue if postprocessing requires that the magnet be plated or coated. The slight field that the magnet picks up can attract debris during the plating or coating process causing for a potential plating or coating failure or a mechanically out-tolerance condition.

Reversible temperature coefficient

B_r drifts with temperature and it is one of the important characteristics of magnet performance. Some applications, such as interial gyroscopes and traveling wave tubes (TWTs), need to have constant field over a wide temperature range. The reversible temperature coefficient (RTC) of Br is defined as

(∆B_r/B_r) x (1/∆ T) × 100%.

To address these requirements, temperature compensated magnets were developed in the late 1970s[1]. For conventional SmCo magnets, B_r decreases as temperature increases. Conversely, for GdCo magnets, Br increases as temperature increases within certain temperature ranges. By combining samarium and gadolinium in the alloy, the temperature coefficient can be reduced to nearly zero.

Coercivity mechanism

In SmCo₅ magnets are fabricated by packing wide-grain lone-domain magnetic powders. All of the motes are aligned with the easy axis direction. In this case, all of the domain walls are 180 degrees. When there are no impurities, the reversal process of the bulk magnet is equivalent to lone-domain motes, where coherent rotation is the dominant mechanism. However, due to the imperfection of fabricating, impurities may be introduced in the magnets, which form nuclei. In this case, because the impurities may have lower anisotropy or misaligned easy axis, their directions of magnetization are easier to spin, which breaks the 180° domain wall configuration. In such materials, the coercivity is controlled by nucleation. To obtain much coercivity, impurity control is critical in the fabrication process.

Series 2:17

These alloys (written as Sm₂Co₁₇, or SmCo Series 2:17) are age-hardened with a composition of two atoms of rare-earth samarium and 13–17 atoms of transition metals (TM). The TM content is rich in cobalt, but contains other elements such as iron and copper. Other elements like zirconium, hafnium, and such may be added in small quantities to achieve better heat treatment response. By weight the alloy will generally contain 25% of samarium. The maximum energy products of these alloys range from 20 to 32 MGOe. These alloys have the best reversible temperature coefficient of all rare earth alloys, typically being -0.03%/°C. The "second generation" materials can also be used at higher temperatures ^[1].

Coercivity mechanism

In Sm₂Co₁₇ magnets, the coercivity mechanism is based on domain wall pinning. Impurities inside the magnets impede the domain wall motion and thereby resist the magnetization reversal process. To increase the coercivity, impurities are intentionally added during the fabrication process.

Machining samarium cobalt

The alloys are typically machined in the unmagnetized state. Samarium-cobalt should be ground using a wet grinding process (water based coolants) and a diamond grinding wheel. The same type of process is required if drilling holes or other features that are confined. The grinding waste produced must not be allowed to completely dry as samarium-cobalt has a low ignition point. A small spark, such as that produced with static electricity, can easily commence combustion. The fire produced will be extremely hot and difficult to control.

Hazards

• Samarium-cobalt magnets can easily chip; eye protection must be worn when handling them.
• Keep them away from children.
• Allowing magnets to snap together can cause the magnets to shatter, which can cause a potential hazard.
• Samarium-cobalt is manufactured by a process called sintering, and as with all sintered materials, inherent cracks are very possible. Design engineers must not expect the magnet to provide mechanical integrity; instead the magnet must be utilized for its magnetic functions and other mechanical systems must be designed to provide the mechanical reliability of the system.

Attributes

• Resistant to demagnetization
• Good temperature stability (maximum use temperatures between 250 and 550 °C; Curie temperatures from 700 to 800 °C)
• A high outlay material (cobalt is market price sensitive)

Material properties^[2]

• Density: 8.4 g/cm³
• Electrical resistivity 0.8×10⁻⁴ Ω·cm
• Coefficient of thermal expansion (perpendicular to axis): 12.5 µm/(m·K)

Uses

• Fender is using one of legendary designer Bill Lawrence's latest designs named the Samarium Cobalt Noiseless series of pickups (SCN) in Fender's American Deluxe Series Guitars and Basses.^[3]
• High-end electric motors used in the more competitive classes in Slotcar racing.
• Turbo-machinery.
• Traveling-wave tube.
• Applications that will require the system to function at cryogenic temperatures or very hot temperatures (over 180°C).
• Applications where performance is required to be consistent with temperature change. The flux density of a samarium cobalt magnet will vary under 5% per 100°C change in temperature (in the range of 25–250°C).

See also

• Neodymium magnet

References