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Trimethylgallium

 
Wikipedia: Trimethylgallium
Trimethylgallium
IUPAC name
Identifiers
CAS number [1445-79-0]
Properties
Molecular formula Ga(CH3)3
Molar mass 114.827 g/mol
Appearance clear colourless liquid
Melting point

−15 °C

Boiling point

55.7 °C

Hazards
Main hazards pyrophoric
Except where noted otherwise, data are given for
materials in their standard state
(at 25 °C, 100 kPa)

Infobox references

Trimethylgallium, Ga(CH3)3, often abbreviated to TMG, is the preferred metalorganic source of gallium for metalorganic vapour phase epitaxy (MOVPE) of gallium-containing compound semiconductors, such as GaAs, GaN, GaP, GaSb, InGaAs, InGaN, AlGaInP, InGaP and AlInGaNP.

TMG is a clear, colorless, pyrophoric liquid[1]. Even the hydrocarbon solutions of TMG, when sufficiently saturated, are known to catch fire on exposure to air. TMG is known to react violently with water and other compounds that are capable of providing labile active hydrogen (i.e. protons). Therefore, TMG needs to be handled with care and caution, e.g. stored in a cool, dry place at 0 to 25 °C, under inert atmosphere, and ensuring that storage temperatures would not exceed 40 °C to avoid deterioration.

References

  1. ^ Journal of Crystal Growth (2004); doi:doi:10.1016/j.jcrysgro.2004.09.007

External links


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