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Stardust Dragon negates and destroys the card it is used against. Prime Material Dragon can only be used against an effect that destroys a monster on the field. So, if Stardust Dragon is trying to negate a Dark Hole, then Prime Material Dragon cannot be used against it. But if it is trying to destroy a Dark Armed Dragon, then Prime Material Dragon can be used against Stardust Dragon in this case.

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Q: Can 'Prime Material Dragon' destroy 'Stardust Dragon' when he uses his special ability?
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