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How does a buffer regulate pH?

Updated: 8/10/2023
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10y ago

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A buffer is used to resist changes in pH and maintain a system at a near-constant pH when small amounts of acids or bases are added. A buffer is made up of a weak acid and its conjugate base (or a weak base and its conjugate acid) existing in equilibrium. When a strong acid is added to the buffer, it will be neutralized by the conjugate base and when a strong base is added to the buffer, it will be neutralized by the conjugate acid. Therefore if too much acid or base is added, the buffer can be overwhelmed and lose its buffering capability. For example: A buffer's pH is given by the Henderson-Hasselbach equation: pH = pKa + log([A-]/[HA]) where pKa is the pKa of the conjugate acid, [A-] is the concentration of the conjugate base, and [HA] is the concentration of the conjugate acid. If 1 L of 1 M acetic acid (weak acid, pKa = 4.76) and 1 L of 1 M sodium acetate (conjugate base) is mixed to produce 2 L of acetate buffer, and the pH of this buffer is: pH = 4.76 + log(0.5M/0.5M) = 4.76 + log(1) = 4.76 (the new concentrations are 0.5 M since each 1 M solution is now in 2 L of solution) If 100 mL of 1.0 M HCl, or 0.1 mol of HCl, is added to the buffer, it is going to react with 0.1 mol of sodium acetate to produce 0.1 mol of NaCl and 0.1 mol of acetic acid. This would mean that the new conjugate base concentration is (1.0-0.1)/2 = 0.45 M = the new weak acid concentration is (1.0+0.1)/2 = 0.55 M. Therefore the new pH of the buffer is: pH = 4.76 + log(0.45M/0.55M) = 4.67 The difference is only 0.09 pH units! Compare that to adding 100 mL of 1.0 HCl to 2 L of water: Initial pH of water: 7.00 After addition of 0.1 mol of HCl, the concentration of H+ is 0.1/2 = 0.05 M The final pH is then -log(0.05M) = 1.30 The difference is a whopping 5.70 pH units!

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15y ago
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10y ago

Buffers resist a change in pH. They do this as a weak acid and a salt of the compound. A buffer contains particles that can bind to substances and thereby neutralize them.

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10y ago

A buffer can control the PH of the solution by stopping the massive changes in the PH levels.

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6y ago

The principle is the equilibrium between the acid and his conjugate base.

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Adding a buffer solution.

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Q: How does a buffer regulate pH?
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What does a buffer regulate?

The pH ( or the concentration of H+ ions) of the medium. A buffer is an aqueous solution consisting of a mixture of a weak acid and its conjugate base or a weak base and its conjugate acid. Its pH changes very little when a small amount of strong acid or base is added to it and thus it is used to prevent any change in the pH of a solution . Buffer solutions are used as a means of keeping pH at a nearly constant value in a wide variety of chemical applications. Many life forms thrive only in a relatively small pH range so they utilize a buffer solution to maintain a constant pH. One example of a buffer solution found in nature is blood.


What happens to the buffer solution pH 7 when acid is added?

When acid is added to a buffer solution at pH 7, the pH of the buffer solution will decrease. However, due to the presence of a conjugate base in the buffer solution, the buffer will resist the change in pH and try to maintain its original pH value. This is because the conjugate base will react with the acid and prevent a significant decrease in pH.


Why does the pH of an acetate buffer increases after dilution with water?

The pH of water is approximatly 7 (a neutral pH), and the acetate buffer has an acidic pH (less than 7) so when you add distilled water to the buffer the pH will increase.


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What is a chief function of carbonic acid in the body?

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