Win the lottery at the lilycove dept store.
Can be obtained from the daily lottery in Goldenrod Radio Tower and i think Goldenrod 6th floor daily drawing.
the only ways to get a second masterball in Pokemon diamond and pearl is to migrate a Pokemon holding a masterball from another Pokemon game (you can repeatedly start new games and migrate the Pokemon holding masterballs), get a DS action replay and catch all of the unknown and show the crazy digger guy in the cave them and type in the code "cowfar" (it seriously works though it doesnt look at all like it) for unlimited masterballs, or just start a new game and give a friend you trust who also has Pokemon diamond or pearl the Pokemon with the masterball and trade them back after the new game. the easiest is action replay
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The cast of The True Master - 2010 includes: Sabrina Bowman as Extra Melvin Davis as Master 4 Gavin Herscher as Master 3 Brandon Law as Master 1 Leonard Rycerz as Master 2
You can access the Battle Frontier and you can catch some legendary pokemon.
get one from the galactic boss annd get extra from the lottery if you matchall the numbers
You don't. They're a one time item. The only way is to trade for a Pokemon holding one with your buddies.
action replay
i heard you can talk to the old man inside the house next to pal park. or you can beat the leader in the warehouse, or cheat.
you go to the abandoned ship and you need a Pokemon that knows diveI can type in large bold print too!you can get extra luxury balls by winning a master rank contest after your Pokemon already has the ribbon.
One way is to trade a Pokemon from Pokemon Leafgreen to Pokemon Emerald that is holding a Master Ball. Then, take that Pokemon to the Battle Frontear and in the Battle Tower. Go to the PC and make sure that BOX9 is compleatly empty. Now, deposet that Pokemon with the Master Ball in BOX9. Exit the PC, and save your game. Now take that Pokemon out, go to the last lady on the right and start to enter the challenge. DO NOT choose the Pokemon with the Master Ball when you are entering Pokemon. Then, you will notice a pause right before the lady saves your game. Turn your game off at this point. Turn your game back on and the Pokemon with the Master Ball now has a clone. (the clone also has a Master Ball) Trade both Pokemon back to Leafgreen and you have two Master Balls. This may take a while, but it works, I swear.
iif i undesrtand that you take out the ar then turn the game off and turn on the ds without putting the ar, then no. you will just have extra master balls
Give a Pokemon in Pokemon Emerald, Sapphire, or Ruby a luxury ball to hold and trade to Fire Red. You can get extra luxury balls by winning a master rank contest after your Pokemon already has the ribbon. There is also one luxury ball in the abandoned ship, but you need dive. As far as I know, you cant get the luxery bal without tradeing with the other games I listed, or trade with someone who already has luxury balls. -BubbaJ
Professor Elm gives you a Master ball after you defeat the Blackthorn City Gym. Alternatively, you could give the Master Ball to a Pokemon to hold on a game that has already received the ball, then trade said Pokemon, with Master Ball, to the newer game. Winning extra Master balls is possible by matching all five numbers with the ID Lottery at the Radio Tower in Goldenrod City. The chances of winning them this way is very slim, however.
In the Pokemon Diamond, Pearl, and Platinum games, the only methods of obtaining master balls is through the lottery, or finding one in Team Galactic's headquarters. The Ruin Maniac does not give the player a masterball, but he does allow the player to access an area with extra Unown in the forms of question marks and exclamation points.
ALWAYS carry good Pokemon, lots of ultra or master balls, and hp restoring items. P.S. make sure your lead Pokemon knows a move that will make the Pokemon stay in battle or has a ability that keeps them in.
you can't, I'm sorry to say. Only 1 masterball per game, unless you want to cheat.