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If you assume that the iron is in equilibirum and there are initially as many protons as there are electrons, then the total charge is zero (because the protons and electrons cancel out). Now if you remove one electron (which has negative charge), you leave a net positive charge on the iron because there are more protons than there are electrons. In reality, I think electrons from other nearby iron atoms would fill the void because this "free sea of electrons" is a property of metals.

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Q: If you took away one electron from iron what would the charge of the ion formed be?
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