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PCl5 is covalent in the vapour phase with a trigonal biyramidal shape. It is ionic in the solid consisting of PCl4+ PCl6-

In solution it can be covalent or ionic depending on the solvent.

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11y ago
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13y ago

it has a covalent bond because covalent bonding is between 2 non metals and ionic/electrovalent bonding is between a metal and non metal. Phosporous is a non metal and chlorine is also a non metal... phosphorous pentachloride is basically one phosphorous atom sharing the valence electrons with 5 chlorine atoms in order for each of them to have a full outer shell

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15y ago

phosphorus pentachloride is a covalent bond...

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14y ago

Phosphorus pentoxide is a covalent bond, not a ionic.

-Emiko Bunny

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9y ago

Oddly enough its ionic! PBr4+ Br- in the solid-- it dissociates when heated.

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11y ago

Phosphorus trichloride is covalent

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11y ago

PCl5 is polar covalent.

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Q: Does phosphorus pentachloride have ionic or covalent compounds?
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