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Is vanillin positive in tollens test?

Updated: 4/28/2022
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10y ago

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No.

While vanillin is an aldehyde, which should react with Tollens' reagent to precipitate silver metal, vanillin does not "pass" Tollens' test. Tollens' reagent is very basic (sodium or potassium hydroxide). Vanillin has a phenolic hydrogen (OH bonded to a phenyl ring) which is slightly acidic. Vanillin will react first with the excess hydroxide ions in solution to form a phenoxide salt, which will not participate in the silver-precipitating reaction.

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Q: Is vanillin positive in tollens test?
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Related questions

Why would vanillin test positive in a ferric chloride test?

It would test positive because there is a phenol group in vanillin.


Which reagent vanillin react?

vanillin violently reacts with Bromine in carbon tetrachloride,tollens reagent and aqueous NaOH


Is fructose gives positive test with tollens reagent?

no negative


Is vanillin positive in a ferric chloride test?

yes


Why fructose gives positive tollen reagent test?

Only aldehydes give a positive Tollens test. However, under the strongly basic conditions of the test, alpha-hydroxy ketones can isomerize to aldehydes, so they will also give a positive Tollens test. Fructose is an alpha-hydroxy ketone.


How is a positive tollens test recognised?

A silverish ppt. Called "silver mirror"


Is vanillin positive in DNPH test?

Yes, it contains carbonyl functional group- aldehyde! :)


What is the principles of tollen's test?

The principle of Tollens' test is to distinguish between aldehydes and ketones. It involves the reduction of silver ions to silver metal in the presence of aldehydes, which results in the formation of a silver mirror on the inner surface of the test tube. Ketones do not give a positive Tollens' test because they do not undergo this reaction with silver ions.


What substances give a positive tollens test?

When adding the aldehyde or ketone to Tollens' reagent, the test tube is put in a warm water bath. If the reactant under test is an aldehyde, Tollens' test results in a silver mirror. If the reactant is a ketone, it will not react because a ketone cannot be oxidized easily. A ketone has no available hydrogen atom on the carbonyl carbon that can be oxidized - unlike an aldehyde, which has this hydrogen atom.


Does vanillin gives iodoform test?

No because vanillin is phenolic aldehyde (only acetaldehyde give idoform among all ketones)


Why does the formic acid give positive test with Tollens reagent?

The formic acid is special because doesn't contain an alkyl group but only an atom of hydrogen; so resembles to an aldehyde.


Does the tollens test deal with alkenes?

No, the Tollen's Silver Mirror Test only confirms the presence of aldehydes.