Soryy to disappoint you, but no electric type Pokemon can learn the move block at all. No electric Pokemon can learn mean look either, so you'd have to shoot for a different type of Pokemon I'm afraid.
I hope this answer was helpful to you.
right when a bronzong evolves it learn block.thts the only one i kno and raised that tried learning that move.
Girantina, in Pokemon d/p
nosepass
The only Pokemon who learns it is Rhyperior (lv 61). You get him by trading a Rhydon to a friend with the hold item Protector attached.
Aipom evovles into Ambipom at level 33, after it learns Double Hit at level 32.
Ponyta evolves at lvl 40 in Rapidash, than Rapidash learns immediately Fury Attack. In lvl 41 he learns Fire Blast. In lvl 45 he learns Bounce. In lvl 49 he learns Flare Blitz.
There are move tutors in certain versions that will teach Pokemon Thunder Punch.
Geodude learns Rock Smash by teaching it HM06 in Pokemon Diamond, Pearl, and Platinum.
gengar haunter gastly
It learns it at Lv61 in Platinum.
The only Pokemon who learns it is Rhyperior (lv 61). You get him by trading a Rhydon to a friend with the hold item Protector attached.
Haunter learns Payback at Level 28 in "Pokémon Platinum."
at level 30 when it learns roll out
you'll get a cranidos in the under ground in Pokemon platinum. just keep on levelling it up till it learns headbutt.
Houndoom learns Flamethrower at lvl 48.
In Pokemon platinum it learns it at level 28
Arceus learns Judgment at Level 100 in Pokémon Platinum.
lugia learns aeroblast at lv89 or lv90
It learns it at Level 1. Yup.
You can use Feint (if you have diamond/pearl/platinum, monferno learns it).