When I first saw this question, Kahlua was the first to come to mind. Being ever thorough, however, I decided to research the question further. You actually helped me learn something.
There are two types of coffee liqueurs: those made from vodka (most common) and those made from rum. Tia Maria is the most common brand of rum based coffee liqueur. Kahlua is probably the most popular vodka-based brand in the U.S., but others include DeKuyper, Godiva, Kamona, and Sabroso.
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There isn't a 'key' element in liqueurs, but there is a key element to liqueurs. They all are a distillate of some kind of spirit with other by-products infused into the process (i.e. Irish cream liqueurs are Irish whiskies infused with cream and other flavorings). Most liqueurs are somewhat sweet, but not necessarily sugar infused. Also, the majority of liqueurs range from 10-25% alcohol by volume (20-50 proof). This is not to say that liqueurs can't be higher proof however, as some of the digestifs can range upwards of 100 proof. This can be somewhat confusing, given the fact that there are lots of products in other categories of the spirit world that are 'flavored', but are not considered a liqueur (i.e. flavored vodkas or rums, etc).
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