A Schottky defect is when 2 oppositely charged ions leave their normal lattice positions forming 2 vacancies in the lattice structure.
This contrasts to a Frenkel defect, where 1 ion simple moves from it's normal lattice position to an interstitial site (tetrahedral/octahedral hole).
because the size of ions are enough to show both defects
Any change in the configuration of the lattice of the crystal which causes the crystal structure to deviate from the ideal structure is called a crystal structure. It is of the following types - Point defects Line defects Surface defects volume defects
The defect forms when oppositely charged ions leave their lattice sites, creating vacancies. These vacancies are formed in stoichiometric units, to maintain an overall neutral charge in the ionic solid. The vacancies are then free to move about as their own entities. Normally these defects will lead to a decrease in the density of the crystal.
crystalline defets are present in a crystal due to the presence of impurities.
defects like airburs,colour streaks,flash,flow line, jeeting, etc
Both Frenkel and Schotty defects improve the electrical conductivity of an ionic crystal.
because the size of ions are enough to show both defects
The radius ratio for AgBr is intermediate. Thus it shows both frenkel and schottky defects. The major defect in AgBr is the Frenkel defect. It has a rocksalt structure i.e. CCP lattice of of Br with atoms of Ag occupying all octahedral holes.Ag moves from octahedral to tetrahedral sites causing only cations to precipitate. Schottky defect arise due to missing of ions from their lacttice point and frenkel arise when the mmissing ions occupy interstitial sites. in AgBr, ag+ ion is small in size and when removed from lacttice point they can occupy interstitial site and therefore show both frenkel and schottky defect. SCHOTTKY Defect in AgBr is exhibited due to precipitation of both Cations and Anions.
When the both the cations and anions are absent from the crystal lattice it is called Schottky defect. This defect is shown when the anions and cations have comparable size. The Frenkel defect is shown by ionic molecules when their is a large difference in the size of anions and cations. The smaller anions are very much mobile and they occupy interstitial site. AgBr has cations and anions with comparable size and hence it shows Schottky defect but the Ag+ ion is very much mobile and it easily occupies interstitial place getting dislocated from its original place, that's why the ionic crystal AgBr shows both Schottky and Frenkel defects.
Any change in the configuration of the lattice of the crystal which causes the crystal structure to deviate from the ideal structure is called a crystal structure. It is of the following types - Point defects Line defects Surface defects volume defects
Natural defect are caused naturally,while artificial defects are caused by human activities
Yes, Schottky defects are created when equal number of cations (Na+) and anions (Cl-) are missing from some ionic compound, since they have single charges (= equal, = 1 as absolute value)
What is the difference between hereditary and evironmental defects
hearts with septal defects (holes between pumping chambers)
The defects detection is the validation process. The defects prevention is a verification process.
one is quality of the service and the other is quality of the product. Product quality usually includes features, performance, defects etc. Service quality includes delivery time, knowledge of delivery personnel etc.
The defect forms when oppositely charged ions leave their lattice sites, creating vacancies. These vacancies are formed in stoichiometric units, to maintain an overall neutral charge in the ionic solid. The vacancies are then free to move about as their own entities. Normally these defects will lead to a decrease in the density of the crystal.