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What are the release dates for Jeopardy - 1984 1997-B Teen Tournament Quarterfinal Game 1 14-46?
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Jeopardy - 1984 1997-B Teen Tournament Quarterfinal Game 1 14-46 was released on:
USA: 3 November 1997
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What chemicals are in the alcohol absinth that make it illegal in the US?
The main flavoring ingredient in absinthe is Artemisia Absinthium, commonly called Wormwood. Present in Wormwood is the chemical, alpha-thujone, which is toxic and has a similar molecular geometry to THC, the active ingredient in cannabis. Thus, absinthe is most likely illegal in the United States because it contains alpha-thujone. --Deb This is from the Nation Institute of Health (NIH.gov: Facts about thujone) site linked to the left of this answer:"Regulatory Status: No standards or guidelines have been set by NIOSH or OSHA for occupational exposure to or workplace allowable levels of alpha-thujone. Thujone was not on the American Conference of Governmental Industrial Hygienists (ACGIH) list of compounds for which recommendations for a threshold limit value (TLV) or biological exposure index (BEI) are made. Thujone is potentially toxic and the presence of alpha- and beta-thujone in food and beverages is regulated by law in several countries (Micali & Lanuzza, 1995). The use of thujone as a food additive has been banned in the United States (Rogers, 1981; Galli et al., 1984). The natural flavoring substances wormwood, white cedar, and oak moss may be used in food under the condition that the finished food is thujone-free. Tansy may only be used in alcoholic beverages provided that the finished product is thujone-free, and yarrow use is specified as beverages only, thujone-free (FDA, 1997b).In 1979, the FAO/WHO Codex Committee on Food additives restricted the use of apha- and beta-thujones to the following maximum levels in final products ready for consumption: 0.5 ppm in food and beverages, 10 ppm in alcoholic beverages containing more than 25% alcohol, 5 ppm in alcoholic beverages containing less than 25% alcohol, and 35 ppm in bitters (Galli et al., 1984)."See the Web Links for additional information about absinthe and alpha-thujone.
How Friedrick Froebel influenced curriculum design?
The German educator, Friedrich Froebel, was one of these pioneers of early childhood educational reform. As an idealist, he believed that every child possessed, at birth, his full educational potential, and that an appropriate educational environment was necessary to encourage the child to grow and develop in an optimal manner (Staff, 1998). According to Watson (1997b), Froebel's vision was to stimulate an appreciation and love for children and to provide a new but small world--a world that became known as the Kindergarten--where children could play with others of their own age group and experience their first gentle taste of independence. Watson further adds that this early educational vision laid the foundation for the framework of Froebel's philosophy of education which is encompassed by the four basic components of (a) free self-activity, (b) creativity, (c) social participation, and (d) motor expression.As an educator, Froebel believed that stimulating voluntary self-activity in the young child was the necessary form of pre-school education (Watson, 1997a). Self-activity is defined as the development of qualities and skills that make it possible to take an invisible idea and make it a reality; self-activity involves formulating a purpose, planning out that purpose, and then acting on that plan until the purpose is realized (Corbett, 1998a). Corbett suggests that one of Froebel's significant contributions to early childhood education was his theory of introducing play as a means of engaging children in self-activity for the purpose of externalizing their inner natures. As described by Dewey (1990), Froebel's interpretation of play is characterized by free play which enlists all of the child's imaginative powers, thoughts, and physical movements by embodying in a satisfying form his own images and educational interests. Dewey continued his description by indicating that play designates a child's mental attitude and should not be identified with anything performed externally; therefore, the child should be given complete emancipation from the necessity of following any given or prescribed system of activities while he is engaged in playful self-activity. In summarizing Froebel's beliefs regarding play, Dewey concluded that through stimulating play that produces self-activity, the supreme goal of the child is the fullness of growth which brings about the realization of his budding powers and continually carries him from one plane of educational growth to another.To assist children in their development of moving from one plane of educational growth to another, Froebel provided the children with many stimulating activities to enhance their creative powers and abilities. Froebel designed a series of instructional materials that he called "gifts and occupations", which demonstrated certain relationships and led children in comparison, testing, and creative exploration activities (Watson, 1997b). A gift was an object provided for a child to play with--such as a sphere, cube, or cylinder--which helped the child to understand and internalize the concepts of shape, dimension, size, and their relationships (Staff, 1998). The occupations were items such as paints and clay which the children could use to make what they wished; through the occupations, children externalized the concepts existing within their creative minds (Staff, 1998). Therefore, through the child's own self-activity and creative imaginative play, the child would begin to understand both the inner and outer properties of things as he moves through the developmental stages of the educational process.A third component of Froebel's educational plan involved working closely with the family unit. Froebel believed that parents provided the first as well as the most consistent educational influence in a child's life. Since a child's first educational experiences occur within the family unit, he is already familiar with the home environment as well as with the occupations carried on within this setting. Naturally, through creative self-activity, a child will imitate those things that are in a direct and real relationship to him-things learned through observations of daily family life (Dewey, 1990). Froebel believed that providing a family setting within the school environment would provide children with opportunities for interacting socially within familiar territory in a non-threatening manner. Focusing on the home environment occupations as the foundation for beginning subject-matter content allowed the child to develop social interaction skills that would prepare him for higher level subject-matter contnt in later educational developmental stages (Dewey, 1990).Over one hundred and fifty years ago, Froebel (1907) urged educators to respect the sanctity of child development through this statement:We grant space and time to young plants and animals because we know that, in accordance with the laws that live in them, they will develop properly and grow well. Young animals and plants are given rest, and arbitrary interference with their growth is avoided,/because it is known that the opposite practice would disturb their pure unfolding and sound development; but, the young human being is looked upon as a piece of wax or a lump of clay which man can mold into what he pleases (p. 8).Motor expression, which refers to learning by doing as opposed to following rote instructions, is a very important aspect of Froebel's educational principles. Froebel did not believe that the child should be placed into society's mold, but should be allowed to shape his own mold and grow at his own pace through the developmental stages of the educational process. Corbett (1998b) upholds Froebel's tenets that a child should never be rushed or hurried in his development; he needs to be involved in all of the experiences each stage requires and helped to see the relationships of things and ideas to each other and to himself so that he can make sense out of both his subjective and objective world. Corbett further agrees that development is continuous, with one stage building upon another, so that nothing should be missed through haste or for any other reason as the child moves through the educational process. Responsible educators should strive to recognize each child's individual level of development so that essential materials and activities to stimulate appropriate educational growth can be provided. Froebel believed that imitation and suggestion would inevitably occur, but should only be utilized by the teacher as instruments for assisting students in formulating their own instructional concepts (Dewey, 1990).The Kindergarten idea was first introduced into the United States in the late 1840's (Watson, 1997b), and Froebel's basic philosophic principles of free self activity, creativity, social participation, and motor expression are valuable components which exist functionally, with some modifications, in most current early childhood education programs. The education of society's children is still a difficult and fascinating issue studied by world philosophers. Educators of the future will continue to look to philosophers of the past for assistance in striving to attain the common goal of being jointly responsible for nurturing, educating, and cultivating each child toward his or her maximum potential through the educational process.
Which team has the most national championships in college football?
Conference with Most NCAA Football ChampionshipsHere are some opinions from FAQ Farmers: AlabamaI think the Big8/12 and the SEC are tied at 14 since 1936.When did "Alabama" become a conference?- The Big Ten easily has the most national championships. There are 20 national championships between Ohio State, Michigan, and Minnesota, not even counting the other team's championships in the Big Ten.- Since 1936, these are the results (include dual and tri championships ... thanks AP) based on what conference teams are in now, which of course is a dumb way to consider it. Texas was a Southwestern Conference member for all but one of their titles, etc.1. SEC, 202. Big Ten, 183. Big 12, 174. Non-BCS (Notre Dame, Army, BYU, TCU), 135. Pac-10 & ACC, 96. Big East, 4** All of the above is incorrect. The six conferences listed are Division I. The NCAA does not award a championship for Division I football.
Are ozone generators beneficial in homes?
It depends on who you ask. If you go on amazon and read reviews for ozone generators, some say they work, others say no, but you have to wonder who's writing those reviews. This is a section from the EPA website on the effectiveness of ozone generators:Available scientific evidence shows that at concentrations that do not exceed public health standards, ozone has little potential to remove indoor air contaminants.Some manufacturers or vendors suggest that ozone will render almost every chemical contaminant harmless by producing a chemical reaction whose only by-products are carbon dioxide, oxygen and water. This is misleading.First, a review of scientific research shows that, for many of the chemicals commonly found in indoor environments, the reaction process with ozone may take months or years (Boeniger, 1995). For all practical purposes, ozone does not react at all with such chemicals. And contrary to specific claims by some vendors, ozone generators are not effective in removing carbon monoxide (Salls, 1927; Shaughnessy et al., 1994) or formaldehyde (Esswein and Boeniger, 1994).Second, for many of the chemicals with which ozone does readily react, the reaction can form a variety of harmful or irritating by-products (Weschler et al., 1992a, 1992b, 1996; Zhang and Lioy, 1994). For example, in a laboratory experiment that mixed ozone with chemicals from new carpet, ozone reduced many of these chemicals, including those which can produce new carpet odor. However, in the process, the reaction produced a variety of aldehydes, and the total concentration of organic chemicals in the air increased rather than decreased after the introduction of ozone (Weschler, et. al., 1992b). In addition to aldehydes, ozone may also increase indoor concentrations of formic acid (Zhang and Lioy, 1994), both of which can irritate the lungs if produced in sufficient amounts. Some of the potential by-products produced by ozone's reactions with other chemicals are themselves very reactive and capable of producing irritating and corrosive by-products (Weschler and Shields, 1996, 1997a, 1997b). Given the complexity of the chemical reactions that occur, additional research is needed to more completely understand the complex interactions of indoor chemicals in the presence of ozone.Third, ozone does not remove particles (e.g., dust and pollen) from the air, including the particles that cause most allergies. However, some ozone generators are manufactured with an "ion generator" or "ionizer" in the same unit. An ionizer is a device that disperses negatively (and/or positively) charged ions into the air. These ions attach to particles in the air giving them a negative (or positive) charge so that the particles may attach to nearby surfaces such as walls or furniture, or attach to one another and settle out of the air. In recent experiments, ionizers were found to be less effective in removing particles of dust, tobacco smoke, pollen or fungal spores than either high efficiency particle filters or electrostatic precipitators. (Shaughnessy et al., 1994; Pierce, et al., 1996). However, it is apparent from other experiments that the effectiveness of particle air cleaners, including electrostatic precipitators, ion generators, or pleated filters varies widely (U.S. EPA, 1995).
What did China do and why to increase the air qulity prior to the 2008 olympic?
Atmospheric Environment 41 (2007) 480--492 Air quality during the 2008 Beijing Olympic Games David G. Streetsa,, Joshua S. Fub, Carey J. Jangc, Jiming Haod, Kebin Hed, Xiaoyan Tange, Yuanhang Zhange, Zifa Wangf, Zuopan Lib, Qiang Zhanga,d, Litao Wangd, Binyu Wangc, Carolyne Yua aDecision and Information Sciences Division, Argonne National Laboratory, Argonne, IL 60439, USA bDepartment of Civil & Environmental Engineering, University of Tennessee, Knoxville, TN 37996, USA cOffice of Air Quality Planning & Standards, US Environmental Protection Agency, Research Triangle Park, NC 27711, USA dDepartment of Environmental Science and Engineering, Tsinghua University, Beijing 100084, PR China eCollege of Environmental Sciences, Peking University, Beijing 100871, PR China fInstitute of Atmospheric Physics, Chinese Academy of Sciences, Beijing 100029, PR China Received 13 April 2006; received in revised form 14 July 2006; accepted 19 August 2006 Abstract China is taking major steps to improve Beijing's air quality for the 2008 Olympic Games. However, concentrations of fine particulate matter and ozone in Beijing often exceed healthful levels in the summertime. Based on the US EPA's Models-3/CMAQ model simulation over the Beijing region, we estimate that about 34% of PM2.5 on average and 35--60% of ozone during high ozone episodes at the Olympic Stadium site can be attributed to sources outside Beijing. Neighboring Hebei and Shandong Provinces and the Tianjin Municipality all exert significant influence on Beijing's air quality. During sustained wind flow from the south, Hebei Province can contribute 50--70% of Beijing's PM2.5 concentrations and 20--30% of ozone. Controlling only local sources in Beijing will not be sufficient to attain the air quality goal set for the BeijingOlympics. There is an urgent need for regional air quality management studies and new emission control strategies toensure that the air quality goals for 2008 are met. r2006 Elsevier Ltd. All rights reserved. Keywords:Beijing; Regional air quality; Olympic Games; PM2.5; Ozone1. Introduction Beijing will host the 2008 Summer Games of the XXIX Olympiad from August 8--24, 2008. This is anevent of paramount importance to China, and great steps are being taken to ensure its complete success. Of concern both within and outside China is the air quality that athletes and attendees will face during the Games. China wishes to ensure a healthful and enjoyable experience for all. However, air pollution levels in the summertime in Beijing can be high. Significant improvements in air quality in China were achieved during the late 1990s and early 2000s (Hao and Wang, 2005), but with reinvigorated economic growth and continued expansion of the transportation system, some of those gains havebeen lost in the last few years. The Beijing and National governments are introducing many new pollution control measures designed to reduce local emissions in Beijing, as ARTICLE IN PRESSwww.elsevier.com/locate/atmosenv 1352-2310/$ - see front matter r 2006 Elsevier Ltd. All rights reserved.doi:10.1016/j.atmosenv.2006.08.046 Corresponding author. Tel.: +1630 252 3448; fax: +1630 252 5217.E-mail address: dstreets@anl.gov (D.G. Streets).specified by the Beijing Organizing Committee ofthe XXIX Olympic Games (BOCOG) (2004).Undoubtedly, by August 2008, local sources of airpollution will be considerably fewer than they are today. However, there is a concern that much of the air pollution experienced in Beijing is regional in nature and not attributable to local sources. Thus, control measures implemented only in Beijing may not reduce ambient pollutant concentrations to acceptable levels. The purpose of this study is to examine the contribution of sources outside Beijing to air pollution levels in summertime Beijing. We consider two of the most important regional andurban air pollutants: fine particulate matter (PM) and ozone (O3). We examine the contributions ofneighboring provinces and suggest priorities foraddressing regional air pollution concerns. Fig. 1shows the locations of the Beijing and Tianjin Municipalities that contain the cities of Beijing (population 11.5 million) and Tianjin (9.3 million) (National Bureau of Statistics of China (NBS), 2004). Surrounding them are three largeprovinces---Hebei, Shandong, and Shanxi---all heavily populated, urbanized, and industrialized. Also shown inFig. 1 are the four large urban centers of Shijiazhuang (9.1 million), Qingdao (7.2 million), Jinan (5.8 million), and Taiyuan (3.3 million), which are typical industrial, coal-burning cities within several hundred kilometers of Beijing. In these areas, emission controls on stationary sources and vehicles are not as stringent as in Beijing, and emissions are high. Rural biomassburning has also been identified as an importantcontributor to fine PM concentrations in Beijing(Duan et al., 2004). Emissions from these nearby sources, as well as more distant ones, undergochemical reactions during transport on the prevailingwinds, forming secondary species that pervade the entire region and add to the local pollution in Beijing (Han et al., 2005; Hatakeyama et al., 2005; Luo et al., 2000; Mauzerall et al., 2000). Episodic dust storms in the springtime also contribute to the PM loading in Beijing (Dillner et al., 2006; Xie et al., 2005). Fine PM, here considered as either PM2.5 (particles with average diametersp2.5 micrometers [mm]) or PM10 (diameters p10 mm), is directly emitted from power plants, motor vehicles, industrial facilities, and other sources. It is also formed photo-chemically from reactions of primary gaseous species in the atmosphere, e.g., ammonium sulfate, ammonium nitrate, and secondary organic aerosols formed from reactions among sulfur dioxide,nitrogen oxides (NOx), volatile organic compounds (VOC), and ammonia (Lun et al., 2003;Tang et al., 2005; Zhang et al., 2000). In summertime, the high temperatures and high humidity promote the photochemical formation of ozone (Xiao and Zhu, 2003), exacerbated by the heat island effect (Lin and Yu, 2005). Fine PM and ozone are considered to be the most serious air pollutants of concern in the US today, as well as in most metropolitan areas around the world. It is imperative to reduce the concentrations of these two pollutants during the Olympic Games. 2. Background In 1997 the US Environmental Protection Agency (US EPA) revised the National Ambient Air Quality Standards (NAAQS) that have been established to protect public health and the environment. The revised PM standards include an annualaverage PM2.5 standard of 15 mgm3 and a dailyaverage PM2.5 standard of 65 mgm3, in addition to an annual PM10 standard of 50 mgm3 and a daily average PM10 standard of 150 mgm3 (US Environmental Protection Agency (US EPA), 1997a). China also has ambient air quality standards for PM,codified in 1996, which it classifies according to three grades. China's daily average PM10 standardsare 50 mgm3 (Grade I), 150 mgm3 (Grade II), and 250 mgm3 (Grade III) (China State Environmental Protection Administration (SEPA), 1996; Hao and Wang, 2005). China's annual PM10 standards are ARTICLE IN PRESS Fig. 1. Map of Beijing and the surrounding area, showing the 4-km modeling domain. D.G. Streets et al. / Atmospheric Environment 41 (2007) 480--492 481 40 mgm3 (Grade I), 100 mgm3 (Grade II), and 150mgm3 (Grade III). The Grade II standard is applied to urban areas like Beijing. Thus, Beijing's daily average PM10 standard is the same as for the US. There is no standard in China for PM2.5 atpresent. There have been many measurements of fine PMin Beijing made over the past five years (summarizedin Table 1). These studies have found averagesummertime daily PM10 concentrations to rangefrom 94 to 251 mgm3 (Bergin et al., 2001; Chan et al., 2005). A maximum value of 368 mgm3was measured at the Southern Observational Base (SB)of the Chinese Academy of Meteorological Sciences (CAMS) in August 2003 (Chan et al., 2005). Thus,average concentrations of PM10 in Beijing haveoften exceeded the US NAAQS and China's Grade II standard in recent years. Occasionally, there have been exceedances of China's Grade III standard of 250 mgm3 for daily PM10 concentrations. Daily PM2.5concentrations in Beijing have been found to be very high in comparison to the US NAAQS value of 65 mgm3. Average daily PM2.5 concentrations in recent studies ranged from 91 to 169 mgm3 (Bergin et al., 2001; Chan et al., 2005). Many studies (Dan et al., 2004; He et al., 2001,2004; Sun et al., 2004; Wang et al., 2005; Xu et al., 2005; Zheng et al., 2005) have measured weekly to seasonally averaged concentrations of fine PM, and the summertime measurements are particularlyuseful indicators of recent air quality. The averages of measured daily PM10 concentrations duringsummer range from 150 to 172 mgm3 (Sun et al.,2004). For PM2.5, the averages of measured daily concentrations range from 75 to 145 mgm3across the various studies. It can be concluded that in recent years both PM10 and PM2.5concentrations in the summer months have been consistently above healthful levels. The World Health Organization (WHO) has not issued a guideline for acceptable ARTICLE IN PRESS Table 1 Summary of measurements of fine particle concentrations in Beijing (concentrations reported for periods of a week or longer are averaged from daily values; concentrations shown are average values with ranges given in parentheses) Measurementintervals PM10 concentration(mgm3) PM2.5concentration (mgm3) Monitoring site(s) Time period of measurements ReferenceHourly (4.5--374) 89 (2.9--300) IP (urban) 8/2003 Chan et al. (2005) Daily 167 (52--272) 91 (30--159) CM (urban)251 (177--368) 114 (84--163) SB (suburban) 94 (3.5--179) 169 (19--368) IP, CM, SB (urban/ suburban) 192 136 PU (suburban) 6/1999 Bergin et al. (2001) 150 65 US National Ambient Air Quality Standards (US EPA, 1997a) 50, 150, 250 China Ambient Air Quality Standards (Grade I, Grade II, Grade III) (China SEPA, 1996) Weekly (37--357) TU, CG (urban) 7/1999--9/2000 He et al. (2001) Monthly 99 DS, PU, AP, YL, MT (urb/sub) 7/2000 Zheng et al. (2005) 112 33 BN (urban) 7/2002 Xu et al. (2005)Seasonal (summer) 93 BN, CS, YH, MY, PG (urb/sub)Summer 2001--2003 Wang et al. (2005) 76 CG (urban) Summer 2000 He et al. (2001) 145 BJ (urban) 7/2002--8/2002 He et al. (2004) 104 BN (urban) 7/2001--8/2001 Dan et al. (2004) 122 PG (rural)91 BN, CS, YH (urban) 6/2002--7/2002 172 (24--462) 77 (16--216) BN (urban) Summer 2002--2003 Sun et al. (2004) 170 (51--311) 82 (12--170) CS (urban) 150 (64--276) 75 (15--180) YH (urban) IP ¼ Institute of Atmospheric Physics, CM ¼ Chinese Academy of Meteorological Sciences, SB ¼ Southern Observational Base, PU¼ Peking University, TU ¼ Tsinghua University, CG ¼ Chegongzhuang, DS ¼ DongSi Environmental Protection Bureau, AP ¼ airport, YL ¼ Yong Le Dian, MT ¼ Ming Tombs, CS ¼ Capital Steel Company, YH ¼ Yihai Garden, PG ¼Pinggu, MY ¼ Miyun, BJ ¼ Beijing (unspecified), BN ¼ Beijing Normal University. 482 D.G. Streets et al. / Atmospheric Environment 41 (2007) 480--492 fine PM concentrations, arguing that health effects research does not support setting a threshold below which concentrations are not harmful; that is to say, fine PM is considered harmful even at very low concentrations (WHO, 2006). Fig. 2 depicts in dramatic fashion how poor Beijing's air quality can be and how quickly it canchange. The right photograph shows air quality on October 26, 2005. This was during a period of air stagnation with low wind speeds and no precipitation that caused fine PM to accumulate. The local Air Pollution Index was 176 on this day, equivalent to a PM10 concentration of 300 mgm3. The left photograph shows the situation just three days later, on October 29, 2005, after a period of rain and wind. The API value decreased to 48 and the PM10 concentration was 50 mgm3.Although there are fewer published measurements of ambient ozone concentrations in Beijing than of fine PM concentrations, ozone remains a critically important component of regional air pollution in Beijing. The US NAAQS ozone standard is set at 80 parts per billion (ppb) on an 8-h average (US Environmental Protection Agency (US EPA), 1997b), which replaced a prior 1-h standard of 120 ppb. China's ozone standard is seton an hourly-average basis and was revised in 2000(Hao and Wang, 2005) to 0.16 mgm3 (Grade I),0.20 mgm3 (Grade II), and 0.20 mgm3 (GradeIII). These standards are approximately equivalent to 80, 100, and 100 ppb in the Beijing atmosphere. The WHO guideline (WHO, 2006) for ozone is 60 ppb as an 8-h average. One Beijing study that was reported in the literature measured an average daily ozone concentration in summer of 0.093 mgm3 with a peak value of 0.178 mgm3 (Sun et al., 2004). Hao and Wang (2005)reported that measurements by the Beijing Environmental Protection Bureau showed ozone concentrations in 1998 exceeding the standard on 101 days or 504 hours. The highest measured hourly concentration was 0.384 mgm3. Therefore, as for fine PM, exceedances of the US NAAQS and the China Grade II standard for ozone are common. 3. Methodology In this present work, Beijing's air quality is simulated using the Models-3/Community Multiscale Air Quality (CMAQ) modeling system (Version 4.4), developed by the US EPA (Byun and Ching, 1999). The CMAQ model has received many applications and evaluations in the US and othercountries for regional- and urban-scale air qualitysimulations, integrating a number of air quality issues (particulate matter, ozone, acid deposition, visibility, air toxics, etc.) into a so-called ''oneatmosphere'' approach. The driving meteorological inputs for this work are provided by the fifthgeneration NCAR/Penn State Mesoscale Model(MM5), version 3.6.2. The pollution episode studied is from July 1--31, 2001, with a spin-up period of 5 days starting on June 26, 2001. Neither the requiredmeteorological data nor any PM10 measurementdata are available for the month of August, so we use July as a summertime proxy for the month of August when the Olympic Games will be held. The model was run in a nested grid mode at 36, 12, and ARTICLE IN PRESS Fig. 2. Illustrative example of Beijing's air quality contrasts: October 29, 2005, Air Pollution Index (API) ¼ 48, PM10 concentration 50 mgm3 (left); October 26, 2005, API ¼ 176, PM10 concentration 300 mgm3 (right). D.G. Streets et al. / Atmospheric Environment 41 (2007) 480--492 483 4 km resolutions. The 36-km grid domain consists of all of China, the Koreas, Japan, and parts of India and Southeast Asia; the 12-km domain consists of East China and the Koreas; and the innermost 4-km domain consists of Beijing and surrounding areas (shown in Fig. 1). The model employs 14 vertical layers of varying thickness with denser layers in the lower atmosphere to better resolve the mixing layer. Emissions are taken from the NASA TRACE-P emission inventory (Streets et al., 2003), updated for the city of Beijing to take account of detailed local information on source strengths and locations. Table 2 summarizes the emissions used in the modeling for Beijing, Tianjin, and the threeneighboring provinces. Note that these five provincestogether contribute 16--32% (depending on species) of China's total national emissions. Though the CMAQ model has received extensive evaluation in the US and other countries, it has not previously been applied in China. The atmosphere of eastern China poses a number of challenges, including the complex mesoscale meteorologycaused by rapidly evolving land-use patterns and the possibly unique interactions between reactive gas-phase species like ozone and high loadings of aerosols. Model evaluation is made more difficult by the absence of routine monitoring data for species like ozone and fine PM. Historical measurements have focused on regulated pollutants like SO2 and TSP, and recently PM10 and NOx/NO2 have been added in some areas. But there are only scattered measurements of PM2.5 and ozone for limited time periods at one or two research sites.The CMAQ model was initially evaluated by comparing predicted daily PM10 concentrations for July 2001 against Air Pollution Index (API) data measured by the Beijing Environmental Monitoring Center (Fig. 3). In addition, predicted PM2.5 concentrations were compared against a set of weekly measurements of PM2.5mass and component species obtained at a monitoring site located at Tsinghua University, Beijing. In general, the agreement between modeled and observed data was good, and the model was able to capture the trends ARTICLE IN PRESS Table 2 Emissions of major anthropogenic species in the study region in July 2001 Region Area (104 ha)a Anthropogenic emissions (Ggmo1)SO2 NOx CO2 b CO CH4 NMVOC NH3 PM10 PM2.5 Beijing Municipality 164 26.5 17.7 5.29 195 17.2 28.3 12.5 5.50 2.27 Tianjin Municipality 119 34.1 22.7 4.79 142 15.0 22.7 9.91 6.71 2.63 Hebei Province 1884 106 58.7 18.7 545 155 72.0 151 38.6 16.6 Shandong Province 1571 154 66.7 19.4 534 192 90.6 164 48.0 22.8 Shanxi Province 1567 114 45.2 12.8 265 136 33.4 26.6 13.6 4.99 Regional total (C103) 435 211 61 1680 515 247 365 112 49 All China (C103)c 1699 946 318 9646 3196 1453 1131Regional share (%) 26 22 19 17 16 17 32 aFrom China Statistical Yearbook (2004). bEmissions in Tgmo1. cOne-twelfth of annual emissions (no monthly variation included) for 2000 (Streets et al., 2003). PM10 and PM2.5 emissions were not reported in that work.200 150 City of Beijing Olympic Stadium Site 100 50 0 0 50 100Observation CMAQ Simulation 150 200 Fig. 3. Comparison of CMAQ model simulations for PM10concentrations in the City of Beijing and at the Olympic Stadium site against observations derived from API data.484 D.G. Streets et al. / Atmospheric Environment 41 (2007) 480--492 of daily and weekly variations of PM2.5 and PM10. The model slightly under-predicted PM2.5 and PM10 concentrations, which might be due to an underestimation of local emissions but could be a model resolution issue; observations are based on a sparse set of point measurements, whereas model simulations are based on a volume average over unit gridcells. The performance of MM5 was also tested against wind and temperature data for the city of Beijing with good results. Temperature simulations, which are particularly important for ozone prediction, agreed withino5%. However, for the time being, very limited ozone measurement data are available for July 2001 to conduct further model evaluations. Because ozone and PM2.5 are such critical pollutants for human health, we recommend routine observations in cities like Beijing, so that their formation can be better understood, their spatial and temporal extent modeled with confidence, and effective mitigation measures designed. 4. Results The model was used to simulate PM2.5 and ozone concentrations in Beijing and surrounding areas. Fig. 4 (top two frames) shows base-case simulations of concentrations in the 4-km model domain. A second model case was run in which all man-made emissions in Beijing were removed (natural emissions such as biogenic VOC emissions were notremoved). The resulting PM2.5 and ozone concentrations are shown in the center two frames ofFig. 4. These two center frames can be considered torepresent the contributions of sources outside Beijing to concentrations inside Beijing. The differences between these two sets of runs (shown in the bottom two frames) can be used to approximately represent the contributions of Beijing sources alone. Note that this approach cannot accurately reflect the contributions of Beijing sources alone, due to the non-linearity of model response to emissionchanges, especially for ozone. Fig. 4 shows that monthly average PM2.5 concentrations under base-case conditions are in excess of 30 mgm3 over most of the Beijing Municipality, rising to 470 mgm3in the Beijing urban center. The steep concentration gradients reveal the important role of local urban sources in determining the ambient PM2.5 level. Sources outside Beijing (center left frame of Fig. 4) contribute a consistent level of 420 mgm3 to Beijing PM2.5 levels. The contribution of Beijing sources alone is 430 mgm3 over a wide area of urban Beijing and 460 mgm3 in the city center. Ozone shows a broader and more spatially variable signature thanPM2.5. Under base-case conditions, maximumhourly ozone concentrations are 490 ppb for much of the area comprising Beijing, Tianjin, andadjacent Hebei Province. The center right frame of Fig. 4 shows that ozone concentrations can be 60--90 ppb even with man-made Beijing emissions removed. Based on very limited observational data for ozone in Beijing, we believe that the predicted concentrations of ozone in Beijing may be slightly underestimated. This may be due to an underestimation of VOC emissions---either anthropogenic (Streets et al., 2003) or biogenic (see Palmer et al., 2003). For example, modeled VOC/NOx ratios in Beijing in this study are typically about six, whereas ratios in the US are typically 10--15 (Kang et al., 2004). On the other hand, an underestimation of CO emissions may be responsible (Streets et al., 2006) on the evidence that oxidation of CO is thought to be the largest source of ozone in eastern China (Tie et al., 2006). Improved regional emission inventories are needed to answer these questions. In order to examine the implications for theOlympic Games, daily average concentrations ofPM2.5 and maximum hourly ozone concentrationswere extracted from the model for the grid cell in which the Olympic Stadium is located. (The site of the Olympic Stadium is between the fourth and fifth ring roads, due north of the city center.) For each day of the month, concentrations resulting from the inclusion of emissions from all sources are contrasted with those for which man-made emissions from Beijing sources are removed (Fig. 5). For the Olympic Stadium site, the average of the simulated daily PM2.5 concentrations is 77 mgm3 (range of 27--130 mgm3) for all sources and 26 mgm3 (2--60 mgm3) for the contribution from sources outside Beijing. These results suggest that sources outside Beijing contribute, on average, about 34% of the measured PM2.5 in the vicinity of the site of the Olympic Games in summertime. The July 2001 simulations show that PM2.5concentrations exceeded the US NAAQS for PM2.5 (65 mgm3) on many days (highest values of 130 and 115mgm3); and, even when all Beijing sources were removed, the highest daily averages in the month (56 and60 mgm3) were close to the US standard. (Recall that China has no PM2.5 standard.)ARTICLE IN PRESS D.G. Streets et al. / Atmospheric Environment 41 (2007) 480--492 485 The ozone simulations show that maximum hourly ozone concentrations exceeded the China Grade II standard of 100 ppb for one episode at the Olympic Stadium (July 6, 117 ppb) and came very close to 100 ppb on two other occasions (July15 and 20). The influence of regional sources is morepronounced than for PM2.5 and more complex.Simulations show considerable day-to-day fluctuation of maximum hourly ozone concentrations within a range of20--120 ppb. Simulations with Beijing man-made emissions removed show more stable values of 50--80 ppb, reflecting the largescale buildup of ozone in eastern China during the summertime (Mauzerall et al., 2000;Luo et al., 2000). When ozone concentrations are high (i.e., July 6, 10, 11, 15, 20, and 25), the contribution of regional sources is in the range of 30--70% at the Olympic Stadium site, depending on the assumedvalue of the global background ozone concentration. Fig. 6 shows the sensitivity of the regional contributions on those six days to global background concentrations in the range of 25--45 ppb. We choose 40 ppb as the most likely value, based on US EPA's modeling guidance and analysis by Tie et ARTICLE IN PRESS 60.0 90 120.0 90 90.0 60.0 30.0 0.0 45.030.0 15.0 0.0 ug/m3 1 90 ppbV 1 90 1 1 60.0 90 120.0 90 90.0 60.0 30.00.0 45.0 30.0 15.0 0.0 ug/m3 1 90 ppbV 1 90 1 1 60.0 90 120.0 90 90.060.0 30.0 0.0 45.0 30.015.0 0.0 ug/m3 1 90 ppbV 1 90 1 1Fig. 4. CMAQ model simulations of monthly average concentrations of PM2.5 (left) and maximum hourly concentrations of ozone (right) in the Beijing area for July 2001. Top frames show simulations for emissions from all sources; center frames show contributions from sources outside Beijing (Beijing emissions removed); bottom frames show the differences between top and center frames, which may be considered to approximately represent the contributions from Beijing sources alone (see text). 486 D.G. Streets et al. / Atmospheric Environment 41 (2007) 480--492 al. (2006) of ozone concentrations in eastern China; assuming 40 ppb, the regional contribution is 35--60%. Note that the regional contribution is not correlated with the magnitude of the ozone concentration. For a number of days (notably July 3, 9, 21, 24, and 27), the model simulates higher ozone concentrations when man-made Beijing emissions areremoved. This phenomenon is often observed in urban environments, when intense NOx emissions from local sources titrate, or consume, ozone under certain meteorological conditions, and reflects the non-linear nature of model response to emission changes. In such situations, instead of lowering ozone concentrations, reduction of NOx emissions can lead to higher ozone concentrations, sometimes referred to as a NOx ''disbenefit.'' In order to give guidance to China's national and local policymakers, we ran four additional cases designed to elicit information on which surrounding areas influence Beijing's air quality the most in a typical summer month. These runs integrate theemission characteristics of the neighboring sourceregions (e.g., Taiyuan has many poorly controlled ARTICLE IN PRESS PM2.5 0 1/1 1/21/3 1/4 1/5 1/6 1/7 1/81/9 1/10 1/11 1/12 1/131/14 1/15 1/16 1/17 1/181/19 1/20 1/21 1/22 1/231/24 1/25 1/26 1/27 1/281/29 1/30 1/31 7/1 7/27/3 7/4 7/5 7/6 7/7 7/87/9 7/10 7/11 7/12 7/137/14 7/15 7/16 7/17 7/187/19 7/20 7/21 7/22 7/237/24 7/25 7/26 7/27 7/287/29 7/30 7/31 20 40 6080 100 120 140 160 Date (Year 2001) Concentration (ug/m3) 020 40 60 80 100 120140 160 Date (Year 2001) Concentration (ppb) Olympic Stadium Site Olympic Stadium Site (without Beijing Emissions) Ozone Olympic Stadium Site Olympic Stadium Site (without BeijingEmissions) Fig. 5. CMAQ model simulations of daily average PM2.5 concentrations and maximum hourly ozone concentrations at the Olympic Stadium site in Beijing for July 2001. D.G. Streets et al. / Atmospheric Environment 41 (2007) 480--492 487 high-sulfur coal-burning factories, whereas Shijiazhuang is a center of the chemicals industry with high VOC emissions) with important meteorological and topographical factors (e.g., Beijing is framed by hills to the north and west, as shown inFig. 1). We ran the four cases by eliminating all man-made emissions, one region at a time, from Hebei Province, Tianjin Municipality, Shandong Province, andShanxi Province. Table 2 shows that PM2.5emissions from Hebei and Shandong Provinces are 7--10times larger than Beijing's, while PM emissions in Shanxi Province are about double Beijing's and Tianjin has about the same emissions. On an areal basis (Mg 103 ha1mo1), however, PM2.5 emissions are comparable: Beijing 1.38, Tianjin 2.21, Hebei 0.88, Shandong 1.45, and Shanxi 0.32. With regard to ozone precursor emissions, the surrounding provinces are less dominant. Emissions of NOx and VOC relative to Beijing emissions are 2--4 times for Hebei Province and Shandong Province, 1--3times for Shanxi Province, and about the same forTianjin. Fig. 7 shows two examples of the spatial variation of model-simulated percentage contributions ofemissions in Tianjin and Hebei Province to monthlyaverage PM2.5 and peak ozone concentrations inBeijing. Note that these runs were performed at 12- km resolution throughout the east China domain. For PM2.5, it can be seen that Hebei Provincecontributes 30% or more throughout the BeijingMunicipality, whereas Tianjin's contribution ARTICLE IN PRESS 0 10 20 30 4050 60 70 80 25 30 35 40 45Background ozone concentration (ppb) Regional contribution (%) 6-Jul 10-Jul 11-Jul15-Jul 20-Jul 25-Jul Fig. 6. Sensitivity of the regional source contribution to ozone concentrations at the Olympic Stadium site, as a function of the assumed level of background ozone concentration. 50.0 196 50.000 19637.500 25.000 12.500 0.000 37.525.0 12.5 0.0 166 167 % 54 85 % 54 8650.0 196 50.0 196 37.5 25.0 12.50.0 37.5 25.0 12.5 0.0 166 167% 54 85 % 54 86 Fig. 7. Contribution of emissions (%) in neighboring provinces to monthly average PM2.5concentrations (left) and peak ozone concentrations (right) in Beijing, according to CMAQ model simulations for July 2001. Top: Tianjin; bottom: Hebei. 488 D.G. Streets et al. / Atmospheric Environment 41 (2007) 480--492 averages 10--20%, mostly to the eastern part of the Beijing Municipality. For ozone, the contributions are lower, with Hebei Province contributing on average 10--20% to ozone concentrations in the eastern part of Beijing and Tianjin's contribution being less than 10% for most of Beijing.Fig. 8 shows the contributions of each of the fourprovinces to Beijing PM2.5 and ozone concentrations for each day of the month of July. Eachprovince's contribution varies dramatically from day to day, depending on wind direction and other meteorological factors. Modeled wind arrows in Fig. 8 show the wind strength and direction every 6 h at the Olympic Stadium site. It is clear that the dominant wind direction in July is from the south. The peak contributions from Hebei Province (e.g., PM2.5 on July 29) and from Tianjin and Shandong Province (e.g., ozone on July 24) are preceded by several days of persistent wind from the south and southeast; in contrast, the low contributions fromeach of the four provinces on July 6 are preceded bydominant winds out of the northeast. Hebei Province shows the greatest contribution to PM2.5 concentrations in Beijing, reaching as high as 70% and averaging 32% for the entire month. Under certain meteorological conditions, Shandong ARTICLE IN PRESS 70 Provincial Contribution (%) Provincial Contribution (%) Date (Year 2001) 60 PM2.5 Ozone 5040 30 20 10 40 3530 25 20 15 10 5 00 7/1 7/2 7/3 7/4 7/57/6 7/7 7/8 7/9 7/10 7/117/12 7/13 7/14 7/15 7/167/17 7/18 7/19 7/20 7/217/22 7/23 7/24 7/25 7/267/27 7/28 7/29 7/30 7/31Hebei Shanxi Tianjin Shandong Fig. 8. CMAQ model simulations of the contributions of neighboring provinces to daily average PM2.5 (upper) and maximum hourly ozone (lower) concentrations at the Olympic Stadium site in Beijing for July 2001. Also shown are modeled 6-hour wind arrows for the Olympic Stadium site. D.G. Streets et al. / Atmospheric Environment 41 (2007) 480--492 489Province (highest contribution 63%, average 11%) and Tianjin Municipality (highest contribution 42%, average 13%) also exert a significant influence. Shanxi Province, due to meteorological and topographical factors, shows less effect (maximum contribution 21%, average 3.5%). The influences on ozone concentrations are less pronounced, withmaximum contributions of 28% for Hebei Province, 27% for Tianjin Municipality, 24% for Shandong Province, and 10% for Shanxi Province (but not at the same time). Because of the wide day-to-day fluctuations in the contributions to ozone concentrations, we do not present average values for ozone. Limited modeling studies by Chinese researchersof ozone formation in the Beijing area have reachedsimilar conclusions (Wang and Li, 2002, 2003).Wang and Li (2002) used the CAMx model to studythe contributions of anthropogenic hydrocarbons to ozone formation in urban and suburban Beijing. They found that prevailing winds in summer daytime are from the south and southeast and that there is a definite regional contribution to both peak and average ozone concentrations in Beijing. Wang and Li (2003) found that emissions in Tianjin contributed 10--33% of the ozone in Beijing, while emissions in Hebei Province contributed 6--13%. Shandong and Shanxi Provinces had littlecontribution during the 2-day period of theirsimulations. Tang (2004) confirmed these results for a single day of Wang and Li's simulation(2003), reporting that emissions in Tianjin contributed33% to ozone formation in downtown Beijing, while emissions in the southern part of Hebei Province contributed 11%. The weight of evidence from all model simulations is that the regional contribution to Beijing's air quality is almost always significant in the summertime and sometimes very large. Cities like Beijing are trying hard to improve environmental controls and reduce emissions in the face of rapid economic development. By thebeginning of the 21st century, Beijing had implemented a number of measures to improve air quality: increasing access to natural gas, electricity, and geothermal energy; converting all coal-burning stoves and residential boilers to cleaner energy; and enforcing more stringent emission standards for vehicles (BOCOG, 2004). This resulted in a decline in measured SO2 and TSP concentrations---though values still exceeded Grade II standards, and NOx levels were generally on the rise (Hao and Wang, 2005). Now China has announced further major renovation and restructuring programs in Beijing aimed at meeting the national standards by 2008,including reducing coal consumption, installing emission control equipment, increasing natural gas use, tightening vehicle emission standards, and introducing airborne PM and evaporative VOC controls. The specific objectives for the Olympic Games period are (a) that concentrations of SO2, NO2, and O3 should meet WHO guidelines; and (b) that particle concentrations should be comparable to levels in major cities in the developed countries (BOCOG, 2004). 5. ConclusionsThere is no doubt that the measures planned to limit air pollution in Beijing will greatly improve Beijing's air quality for the period of the 2008 Olympic Games. But will they be sufficient to achieve the stated objectives? This study shows that, even in the limit that Beijing generates no manmade emissions, levels of fine PM and ozone couldstill be high and could exceed healthful levels underunfavorable meteorological conditions. Because the limit of zero emissions cannot be achieved in practice, and because China is presently undergoing tremendous economic growth, the threat of higher regional emissions and higher concentrations of fine PM and ozone by 2008 is very real. Air quality in Beijing in the summertime isdictated by meteorology and topography. Typically,temperatures are high, humidity is high, wind speeds are low, and the surrounding hills restrict venting of pollution. Thus, regional pollutants like PM2.5and ozone build up over several days--- usually until dispersed by wind or removed by rain. Our modeling suggests that emission sources far from Beijing exert a significant influence on Beijing's air quality. We recommend new measurement and modeling studies to further investigate the nature of regional air quality in China, as well as theconsideration of additional emission control measures for Beijing's neighboring provinces in plans for healthful air during the 2008 Olympic Games. Acknowledgments The authors acknowledge the support of the US EPA's Intercontinental Transport and Climatic Effects of Air Pollutants (ICAP) project. The authors also thank Joe Paisie of US EPA for permission to use the photographs inFig. 2.
