I suspect you have some loose or worn belts. Check the wear and tension, adjust and/or replace them. Probably the power steering belt. John In MontanaAnswermost likely that first answer is correct. In the morning, your alternator needs more energy to charge the battery up from sitting over night. So it takes more power to turn the alternator, putting more stress on the belt, causing a loose or worn one to squeal until the battery is near or at full charge. just try getting the drive belts tightened, if that doesnt work, get new ones on.
Start with the most likely andeasiest to fix. Check your brake pads... There is a wear indicator on the inside pads (closest to engine) that will rub on the rotor and make a squealing noise to warn you that the pads are getting thin. When you apply the brakes the noise will go away a lot of the time. If the pads are new or not making the noise then I do not know what the problem may be.
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