I'm not sure what happens when you add nacl, but kscn and hcl reacts to from an intensely red color in the presence of iron.
k2co3 + 2hcl --> kcl +h2o +co2
To make a potassium thiocyanate solution, dissolve 0.972 g potassium thiocyanate (KSCN) in enough water to make 100 ml.
When you are looking to make a potassium thicyanate solution you have to dissolve 0.972 g of KSCN in enough H2O to make a 100 mL solution.
FeCl3 + 6KSCN --> [Fe(SCN)6]-3 + 6K+ + 3Cl- This is a complex ion equation. K has a charge of +1 and Cl has a charge of -1 but since these form an aqueous solution, they are seperated. Put together, the equation cannot be balanced.
On addition of the KI to your copper (II) solution, you formed Copper (I) iodine solid and produced the tri-iodide ion. It is the tri-iodide ion that you are titrating with the sodium thiosulfate. The tri-iodine ion is what itercalates into the starch molecules to form the dark blue color you are using as an end point in the titration. Some the the tri-iodide ion formed will adsorb to the surface of the solid copper (I) iodine formed. This must be desorbed for a complete titration. The addition of the potassium thiocyanate, displaces the adsorbed tri-iodine ion, and liberates it for titration.
This is chemical change; this reaction is used as qualitative test for iron - a blood red color appear in solution.
With anything that contains Fe (3+) ions :-)
FeCl3 +KSCN + AgNO3
If tap water turns a deep red color with a few drops of potassium thiocyanate (KSCN), it indicates the presence of iron(III) cations (Fe3+).
Iron (III)
Yes.. it is solid KSCN melted, so the ions transport the electricity. In the other hand solid KSCN would not transport any electricity.
Yes
Na2CO3 is added to prevent oxidation of cu+ ions which are repeatedly formed by reaction of Cu++ and I-.So, to prevent oxidation co2 is used in retarding reaction
potassium thiocyanate
10 g KSCN; add distilled water for a total volume of 1 L
potassium thiocyanate
We usually heat KSCN Fe solution before titration with EDTA so as to produce crystalline crust forms.