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obviously S03 idiot cause it has a higher IMF due to its dipole to dipole and more oxygens. even so, it has a higher mass and you should at least check wikipedia lol, it has the numbers

WHOEVER wrote the above comment is stupid. SO3 doesnt have dipole dipole retard cuz it isn't polar. The fact that SO3 has a higher b.p. than SO2 is b/c the LDF (London dispersion force) of SO3 is a greater IMF than the dipole-dipole force of SO2.

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12y ago
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8y ago

SO2; SO2 has a larger molecular mass than CO2. The most important factor in determining the boiling point, is the intermolecular forces involved. SO2 is a polar molecule with dipole dipole forces. CO2 is a nonpolar molecule, thus having dispersion (London) forces. Dispersion forces are the weakest intermolecular forces so dipole-dipole forces are much stronger. Dipole-dipole forces have a higher melting point because more heat is needed to break it down.

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15y ago

Sulfur dioxide because there are more electrons involved (due to the S over N). Because of the higher number of electrons, it has higher dispersion forces (attractive forces). This means that more energy (heat) is required to unstick the molecules into a different state of matter.

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12y ago

Mp = -72 °C, 201 K, -98 °F

Bp = -10 °C, 263 K, 14 °F

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11y ago

SO2 has a higher boiling pt because it has a greater molecular mass, SO2 is a pola r molecule which forms dipole-dipole forces which increases the boiling point

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11y ago

So2 has the greater dipole moment. It has a dipole moment of 2.2 Debye while So3^(2-) has a dipole moment of 1.3 Debye.

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13y ago

It's obviously So3

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Q: Why so2 has a higher boiling point than CO2?
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