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So you have 0.25 molar Na3PO4. But for every one molecule of Sodium phosphate, you have 3 molecules of sodium. Therefore you have 0.25*3 or 0.75 molar sodium.

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Q: What is the molarity of Na plus ions in a 0.25 M solution of Na3PO4?
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How many grams of Na3PO4 will be needed to produce 425 mL of a solution that has a concentration of Na plus ions of 0.900 M?

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