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A sweet smell indicates engine coolant. It you can't see any leaking from the hoses in the engine compartment, it's probably the heater core. With the smell coming from the vents too, it's most likely the heater core, but rule out easy fixes first.

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Q: What is the problem if you smell a sweet chemical smell under the hood and in the AC vents of your 1996 Chevy pick up?
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