I'm not trying to be rude, just trying to save you some money and anguish, but if you don't have the experience to find the valve, it's better to leave car repair to the professionals. They are however, located 1 in each a/c hose (they both connect to the a/c compressor which is on the drivers side of the engine compartment with a v8) They will be covered with valve covers the size of a large thinble and will be either black or one red and one blue. They have different size threads so you can't mix them up.
Most Sunfires have a 'valve' on the A/C unit that you use to fill the unit with refrigerant. I say valve because it looks like a valve, but really its more of a nozzle. All vehicles from the mid to late 90's and on are forced by law to use only R-134a refrigerant. How much refrigerant your cars unit holds can be determined by finding the refrigerant charge label under your hood. It should be located near or above your A/C unit. The easiest way to ensure no mistakes or damages to your unit is to get a professional A/C fill. But the cheapest way is to buy a can of refrigerant (you can find these at most auto stores and even Wal-Mart) and follow the instructions given in the box. It will show you step by step how to add the refrigerant to your unit.
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