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the reason for dis is that chlorophylls are green pigments

so when light(which actually consists of vibgyor)fall on leaf green light is reflected and thus we see it as green

thus green is not absorbed by the plant and thus does least help for photosinthesis.the other colours of vibgyor ave their gradient of being absorbed.red gets most absorbed(when u watch a green leaf under red light you see it black)and thus helps photosynthesis to the maximum.

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