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First of all, there is no nitrogen in a water molecule. A water molecule consists of one oxygen atom combined with two hydrogen atoms. Also known as H2O. However, it is also true that an oxygen atom is slightly bigger than a nitrogen atom. Oxygen has one more proton, and one more electron than nitrogen does. Neutron quantities vary, since there is more than one isotope of both oxygen and nitrogen.

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Q: Why in a water molecule is the oxygen atom bigger then the nitrogen atom?
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