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Let me start off by saying that the Lithium ion is not less reactive than the Lithium atom. In fact, Li+ is far more reactive than the Lithium atom, which is why it does not exist in its free state. Lithium ions tend to combine with anything it comes into contact with. However, it has a more stable electronic configuration than the Lithium atom, resembling that of a Noble gas(in the case of Li, it is Helium), which is why 1+ is the preferable oxidation state of Lithium.

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13y ago
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12y ago

It is less reactive because lithium has just lost an electron (has become a cation), therefore it's valence shell is filled (like Helium) thus becoming stable.

Li+ is less reactive than Li.

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13y ago

Yes.

The lithium atom has one valence electron which it loses easily, making it highly reactive.

The lithium ion has a full shell of electrons, which is stable an highly unreactive.

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13y ago

Less reactive compared to what? If you meant to ask why Lithium is less reactive than the rest of the alkaline Earth Metals, it is because the Outermost shell of Lithium is the closest to the nucleus, translating to more attraction between the positively charged nucleus and the negatively charged electron. This makes it more difficult for Lithium to lose the electron, in other words, react. Other Alkaline Earth Metals, such as Sodium and Potassium, have more shells, meaning that the electron from the outermost shells is less influenced by the nucleus than in Lithium. This makes it easier to lose this electron, thus the high reactivity of Sodium and an even higher reactivity of Potassium.

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13y ago

because the lithium ion already lost one of its valence electrons, or the electron on its outermost shell, which is the goal of all metals so there is no longer any need for the lithium ion to go through any more reactions.

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13y ago

It has a nobles gas electron configuration.

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10y ago

because it has a negative electric charge

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Q: Why is a lithium ion less reactive than a lithium atom?
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