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You size wire by the current. Various insulations are rated for voltage, temperature and the medium where the wire will be run.

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Q: Will 2.5mm wire conduct 240 volts?
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How many volts does 12-2 wire carry?

240


What is ampere rating of 10 gauge wire at 120 volts and at 240 volts?

30 amps.


What gauge wire you would use to wire a 5kw heater hvac?

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