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Whether or not a reaction occurs is governed by its Gibbs free energy, or spontaneity. We will refer to this as ∆G. When ∆G is less than 0, the reaction is spontaneous and hence it will occur. On the other hand, when ∆G is more than 0, the reaction is not spontaneous and will not take place.

∆G is governed by several factors:

1) ∆H - the enthalpy of the reaction. This is what you mean by reactions that release energy. These energy-releasing reactions are termed as "exothermic reactions".

2) ∆S - the entropy of the reaction.

3) T - the temperature.

They are inter-related with the formula: ∆G = ∆H - T*∆S

Therefore, the enthalpy of a reaction cannot determine its spontaneity as there are other factors (∆S and T) to consider as well. You also have to take note of activation energy barriers that have to be overcome before a reaction can take place!

I hope this was helpful! :)

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Q: Will exothermic energy-releasing chemical reactions not occur?
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