The last US $100 bills featuring a US president were printed in the 1878 series and carried a portrait of James Monroe.
Since 1914, US $100 bills have had a portrait of Benjamin Franklin. He was of course a statesman, philosopher, inventor, ambassador, scientist, and Founding Father but never served as president.
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The ten dollar bill bears the portrait of Alexander Hamilton, a non-president. The 100 dollar bill carries a portrait of Benjamin Franklin, also not a president.
Benjamin Franklin on the 100 dollar bill.
The President who was on the thousand dollar bill was Grover Cleveland. The President on the five thousand dollar bill was James Madison.
President William McKinley. was on the 500 dollar bill
The front of the US $100 bill shows a picture of Benjamin Franklin. He was a Founding Father, scientist, philosopher, diplomat, and essayist but never served as President.