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countries were confident that allies would fight with them if they declared war.
The main opponents of the Cold War were the United States and the Soviet Union. These countries never actually fought in the battle sense, so the war did not become "hot" between them.
Ukraine became independant on 1992, when the Soviet Union collapsed. Along with all of the other 14 countries that became independant republics.
The United States and the Soviet Union
There were too many countries around the world to name to answer your question. It would be easier to name the communist countries and then you can figure out which countries around the world were not communist countries. These were the communist countries: China, North Korea, The Soviet Union and all its captured countries from World War 2 such as Czecholovakia, Romania, Hungary, Yugoslavia, the Baltic Nations, Lithuania, and others. Later Viet Nam became a communist country when the North Vietnamese defeated South Viet Nam. Most of the non-communist countries became part of the United Nations so you can look on the history of their list of countries.