This is because carbon is less reactive than aluminium.

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as a solid

Aluminium cans can give you cold sores only if you immediately drink from an infected persons can.

yes to produce aluminium chloride AlCl3 vapour which is Al2Cl6 . Aluminium(III) in crystalline AlCl3 are six coordinate, on melting or sublimation (at 150C) the molecule assume the molecular form Al2Cl6