You can buy special t-shirt transfer paper that you can use with
a regular printer, print out the design on to the paper and then
iron the design on to the tshirt
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Basically its a blanket of heavy hydrogen (deuterium) around a
"regular" atomic bomb.
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There are many different kinds of "design" training. First you
would need to figure out what kinds of design you would like to be
doing. Most colleges offer course on graphic design and even
regular art. Start with your local community college and go from
there.