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There is no way to answer this question, because many factors are involved, including, primarily, ranking and emotional fervor over the players, and the score (e.g., the 128th seeded player defeated the #1 seed; or a total unknown defeated the most popular or #1 seed; or the score of a match was 6-0, 6-0, 6-0). Plus the fact that many of the older matches were not recorded in full by history, so little may be known about one or both of the opponents (i.e., a truly momentous "upset" may have been lost to time). If you were to search the web for the answer to this question, you might find many such answers (n.b., on one such search, I found SEVEN possible and completely different, answers, though some may have been prejudiced, because they were fan or country-specific sites).
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Mexico 1986
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