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I am not sure whether you refer to delta S (change in entropy) or entropy itself. So I'll answer for both.

For S (entropy), which is defined by the function S=kln(omega), where k is Boltzmann's constant and omega is the number of microstates corresponding to a given state, the answer is no. Why? Omega (the number of microstates possible for a certain state) can never be smaller than one. Since Boltzmann's constant is a positive number and ln(omega) will always be greater or equal to zero, entropy will never be negative.

However, when calculating delta S (change in entropy in a thermodynamic process), yes entropy can be negative. Remember entropy is essentially the state of disorder of a system since (on a macroscopic level) the natural progression of the world is from order to disorder. (For example, there are more ways to have a messy room than to have an impeccable, neat room). For the change in entropy to be negative just think of it in terms of the room analogy: initially, it was messy, but then it got neater. The state of disorder of things was lessened. Applying this to a chemistry example:

CO 2 (g)--> CO 2 (s)

An element/compound in a gaseous state always has a greater state of entropy (gaseous molecules are more free to move). However, an element/compound in a solid state has a smaller state of entropy because molecules in a solid are less free to move. Smaller state of entropy - greater state of entropy=negative entropy

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What is the third law of thermodynamics as defined by Ludwig Boltzmann?

"As a system approaches absolute zero, all processes cease and the entropy of the system approaches a minimum value.""it is impossible by any procedure, no matter how idealised, to reduce any system to the absolute zero of temperature in a finite number of operations".Lewis (of Lewis acids and bases fame) and Merle Randall phrased it as"If the entropy of each element in some (perfect) crystalline state be taken as zero at the absolute zero of temperature, every substance has a finite positive entropy; but at the absolute zero of temperature the entropy may become zero, and does so become in the case of perfect crystalline substances."


What is the lowest entropy?

The lowest possible entropy occurs in a system at absolute zero temperature. At this point, the system is in a state of maximal order, with all particles at rest and in perfect arrangement, resulting in zero entropy.


When a system is at equilibrium what is delta S?

At equilibrium, the change in entropy (ΔS) of the system is zero. This means that the system is in a state of maximum entropy where there is no further tendency for change in the system.


What is the 3 law of thermodynamics?

There is no accepted or established "fourth law of thermodynamics". There are, however, numerous authors who have postulated versions of fourth laws to explain certain aberrant phenomena. The following link gives over fifteen different versions of postulated "fourth" laws of thermodynamics: http://www.humanthermodynamics.com/4th-Law-Variations.html


What is the law of entropy?

Entropy is the scientific concept of disorder and randomness that has many broad applications across different branches of physics. While it is not a law itself, it is central to understanding the Second Law of Thermodynamics, as objects that are in thermodynamic equilibrium are at their highest state of entropy.

Related Questions

Describe the conditions necessary for a sample to have zero entropy?

The only way to have zero entropy is to have a temperature of absolute zero.


When is the change in entropy zero?

The change in entropy is zero when a process is reversible, meaning that the system and surroundings return to their original state without any net change in entropy.


When entropy is less than zero the probability of occurrence of such a process in an isolated system is?

I don't think entropy can get less than zero


When does the change in entropy equal zero?

The change in entropy equals zero when a process is reversible, meaning that the system and surroundings return to their original state without any net change in entropy.


Why does water have an entropy of zero when it is at zero kelvin?

At absolute zero temperature, water molecules have no thermal energy to move or vibrate, leading to a highly ordered and structured arrangement. This low energy and high level of order result in minimal entropy, as entropy is a measure of the disorder or randomness in a system.


Which is not apt to increase entropy?

A perfectly ordered crystal at absolute zero is not apt to increase entropy, as entropy tends to increase with higher temperatures and disorder.


What is the third law of thermodynamics as defined by Ludwig Boltzmann?

"As a system approaches absolute zero, all processes cease and the entropy of the system approaches a minimum value.""it is impossible by any procedure, no matter how idealised, to reduce any system to the absolute zero of temperature in a finite number of operations".Lewis (of Lewis acids and bases fame) and Merle Randall phrased it as"If the entropy of each element in some (perfect) crystalline state be taken as zero at the absolute zero of temperature, every substance has a finite positive entropy; but at the absolute zero of temperature the entropy may become zero, and does so become in the case of perfect crystalline substances."


What is the lowest entropy?

The lowest possible entropy occurs in a system at absolute zero temperature. At this point, the system is in a state of maximal order, with all particles at rest and in perfect arrangement, resulting in zero entropy.


When will be entropy negative?

Entropy is a measure of disorder in a system and is always equal to or greater than zero according to the second law of thermodynamics. Entropy cannot be negative in a closed system.


Why is -273point15 degrees C the minimum temperature?

It is absolute zero, the temperature where there is zero energy and zero entropy. This temperature is unobservable.


What is the standard entropy of H ion?

The standard molar entropy of an H+ ion at 25°C is approximately 0 J/mol-K. Since the H+ ion is a single charged particle with no internal degrees of freedom, its entropy is considered to be close to zero.


Which law of thermodynamics relates to a system reaching o degrees k?

A classical formulation by Nernst (actually a consequence of the Third Law) is: It is impossible for any process, no matter how idealized, to reduce the entropy of a system to its absolute-zero value in a finite number of operations.