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Rust iron mixes with oxygen. This happens when water comes in contact with iron because the water conducts the small amounts of current that randomly travel through iron. This in turn causes the hydrogen and oxygen to split and the oxygen is then free to bond with the iron. Salt adds more ions into the water making it a better conductor, so more current passes through producing more oxygen and therefore more rust. Distilled water will not cause rust because H2O alone is not a good conductor.

However with experiments shown distilled water can cause rust on nails because it's properties however you shouldn't take my word for it because I'm just a yr12 chemistry student.

This answer is partly wrong. The oxygen atoms in H20 do not split away from the hydrogen atoms to bond with the metal. The oxygen comes from other sources. There are actually dissolved gases present in the water. The metals obtain the oxygen from the oxygen gas that is dissolved into the water. Additionally, distilled water doesn't make metal rust because to distill water, you boil it away, and boiling water always boils away all dissolved gases that are present in the water. When there is no oxygen in the water the metal is in, it is impossible for rust to form.

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