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yes. A mirror reflects sound with better fidelity than a wall because its surface is harder than most walls.

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A surface may be considered "smooth" if the largest feature of its texture is smaller than about 1/20 of a wavelength. Most walls would easily pass this test. Further, the rigidity of a wall is important in the reflection process. A smooth concrete wall would reflect sound better than one of wood, and that in turn would be better than sheet polystyrene foam.

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