The proper address for a Duke, and thus a Duchess, would be 'Your Grace'.
Note, however, that while a person may be a Duchess, that might not be the only title they have. As an example, Charles, the Prince of Wales is, among other titles, Prince of Wales, Duke of Cornwall, Earl of Carrick and Baron of Renfrew. Thus, he can be addressed as Your Highness, Your Grace, My Lord or Your Lordship, all depending on the situation and/or if he WANTS to use a greater title, and the same applies to his wife, Camilla, Duchess of Cornwall.
It is, however, VERY rude to refer to him by a lesser title if the situation doesn't make it clear that one should.
The web address of the Doris Duke Charitable is: http://www.ddcf.org
The web address of the Museum Of Art At Duke University is: www.nasher.duke.edu
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The address of the Sarah P. Duke Gardens is: Duke University, Durham, NC 27708-0342
When writing to a Duke, the correct form of address is "Your Grace." In the salutation of a letter, you would begin with "Dear Your Grace," followed by the body of the letter. If you are referring to the Duke in the third person, you would use "His Grace" or "the Duke of [Title]." It is important to maintain a formal tone throughout the correspondence.
The wife of a duke is addressed as "Duchess." In conversation, she can be referred to as "Your Grace." When formally introducing her, one would typically say, "Her Grace, the Duchess of [Duke's title]."
The Duke University's (The Fuqua School of Business) address is 100 Fuqua Drive, Durham, North Carolina. They offer several MBA programs like The Duke MBA Daytime, The Duke MBA Cross Continent, The Duke MBA Global Executive and The Duke MBA Weekend Executive.
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Hereditary Grand Duke Guillaume of Luxembourg does not have a publicly available fan mail address. However, you can send correspondence to the official address of the Grand Ducal Court of Luxembourg. The address is: 1, Place Clairefontaine, L-1341 Luxembourg. Keep in mind that any correspondence may be screened and responses are not guaranteed.