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To balance any chemical equation, first ensure that you have the correct formulae for all the reactants and products:

BaCl2 + H2SO4 ------> BaSO4 + HCl

Then work methodically through the equation, making sure that there are the same numbers of each element present on either side of the equation.

In this case, we need an extra chlorine on the right hand side, and an extra hydrogen on the RHS, so the result?

BaCl2 + H2SO4 -------> BaSO4 + 2HCl

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Q: How do you balance the equation BaCl2 plus H2SO4 to BaSO4 plus HCl?
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