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In a redox titration using potassium permanganate, the permanganate ion (MnO4-) acts as the oxidizing agent while the other substance being titrated acts as the reducing agent. The endpoint is reached when all the reducing agent has been consumed, leading to a color change from purple to colorless or light pink. The volume of potassium permanganate solution required to reach the endpoint is used to calculate the concentration of the reducing agent.
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Why does HCl not used to acidify the media in potassium permanganate titration?
HCl is not used to acidify the media in potassium permanganate titration because it can react with potassium permanganate, which can interfere with the titration results. Sulfuric acid is usually preferred as it does not react with potassium permanganate and ensures accurate titration results.
What type of indicator is used during potassium permanganate titration?
Usually there is no indicator needed in potassium permanganate titrations as there will be an excess of manganate ions in the conical flask, turning the solution from colourless to pale pink.
Why ferrous sulphate is not used in redox titration?
Ferrous sulfate is not used in redox titrations because it is easily oxidized by air in a laboratory setting, leading to inaccurate results. It is also easily hydrolyzed in the presence of water, affecting the stability and reliability of the titration. Alternative titrants with more stable and reliable properties, such as potassium permanganate or potassium dichromate, are preferred for redox titrations.
Why potassium permanganate is used as a self indicator in the titration of oxalic acid?
Potassium permanganate is used as a self-indicator in the titration of oxalic acid because the initial pink color of potassium permanganate is decolorized in the presence of oxalic acid due to its reducing properties. The endpoint of the titration is reached when all the oxalic acid has reacted with the potassium permanganate, causing the pink color to persist. This change in color helps in determining the equivalence point of the titration.
What is the mechanism of the redox reaction between potassium permanganate and hydrogen peroxide?
The redox reaction between potassium permanganate and hydrogen peroxide involves the transfer of electrons. In this reaction, potassium permanganate acts as an oxidizing agent, while hydrogen peroxide acts as a reducing agent. The permanganate ion (MnO4-) is reduced to manganese dioxide (MnO2), while hydrogen peroxide is oxidized to water and oxygen gas. This reaction occurs in an acidic solution and is often used as a titration method in analytical chemistry.
Why does HCl not used to acidify the media in potassium permanganate titration?
HCl is not used to acidify the media in potassium permanganate titration because it can react with potassium permanganate, which can interfere with the titration results. Sulfuric acid is usually preferred as it does not react with potassium permanganate and ensures accurate titration results.
What type of indicator is used during potassium permanganate titration?
Usually there is no indicator needed in potassium permanganate titrations as there will be an excess of manganate ions in the conical flask, turning the solution from colourless to pale pink.
Why ferrous sulphate is not used in redox titration?
Ferrous sulfate is not used in redox titrations because it is easily oxidized by air in a laboratory setting, leading to inaccurate results. It is also easily hydrolyzed in the presence of water, affecting the stability and reliability of the titration. Alternative titrants with more stable and reliable properties, such as potassium permanganate or potassium dichromate, are preferred for redox titrations.
Why potassium permanganate is used as a self indicator in the titration of oxalic acid?
Potassium permanganate is used as a self-indicator in the titration of oxalic acid because the initial pink color of potassium permanganate is decolorized in the presence of oxalic acid due to its reducing properties. The endpoint of the titration is reached when all the oxalic acid has reacted with the potassium permanganate, causing the pink color to persist. This change in color helps in determining the equivalence point of the titration.
What is the mechanism of the redox reaction between potassium permanganate and hydrogen peroxide?
The redox reaction between potassium permanganate and hydrogen peroxide involves the transfer of electrons. In this reaction, potassium permanganate acts as an oxidizing agent, while hydrogen peroxide acts as a reducing agent. The permanganate ion (MnO4-) is reduced to manganese dioxide (MnO2), while hydrogen peroxide is oxidized to water and oxygen gas. This reaction occurs in an acidic solution and is often used as a titration method in analytical chemistry.
What is the reaction between potassium permanganate and glycol?
When potassium permanganate reacts with glycol, it undergoes a redox reaction where the potassium permanganate is reduced and the glycol is oxidized. This reaction results in the formation of manganese dioxide and water as products.
Why is HCl not used as catalyst in the standardization of potassium permanganate?
HCl is not used as a catalyst in the standardization of potassium permanganate because it can react with permanganate ions, affecting the accuracy of the titration. The standardization process requires a neutral or slightly basic medium to ensure the permanganate titration proceeds correctly.
What indicators used in redox titration?
Some common indicators used in redox titrations are potassium permanganate (KMnO4), which changes color from purple to colorless in acidic conditions, and potassium dichromate (K2Cr2O7), which changes from orange to green in acidic conditions. Other indicators include starch-iodine complex and ferroin.
How is oxalic acid vs NaOH titration different from oxalic acid vs potassium permegnate titration?
In the titration of oxalic acid with NaOH, the acid-base reaction involves the neutralization of the acid by the base. However, in the titration of oxalic acid with potassium permanganate, the permanganate ion oxidizes the oxalic acid to carbon dioxide. This difference in reaction mechanisms leads to different equivalence points and color changes in the two titrations.
How do you determine the end point of titration involving sodium oxalate and potassium permanganate?
The end point of the titration is typically determined by observing a color change. In the case of sodium oxalate and potassium permanganate, the permanganate ion is a deep purple color, and it will turn colorless once it has reacted completely with the oxalate ion. This color change indicates the end point of the titration.
Why no use indicator in the standardizing potassium permanganate titration?
In the standardization of potassium permanganate titration, an indicator is not used because the titration is self-indicating. This means the solution being titrated changes color at the end point, so an additional indicator is not necessary. It is important to carefully observe the color change to ensure accurate titration results.
What is the Reaction of phenol with potassium permanganate?
When phenol reacts with potassium permanganate in an acidic medium, the purple permanganate solution turns colorless as it is reduced to manganese dioxide. This reaction is a redox reaction where phenol is oxidized to benzoquinone.
