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Once you find a pokemon of the fire type which has something to evolve into, (like a numel or torchic or something) you then go into the items pocket in your bag, select the fire stone, and click use. It will then go to the screen with your party of pokemon. Select the fire pokemon mentioned earlier, and it'll evolve.

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Q: How do you use fire stone in pokemon emerald?
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get eevee and use a fire stone


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