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if ∆EN < 0.5, the substances is non polar covalent

if 0.5 < ∆EN < 1.5 the substance is polar covalent.

if 1.5 < ∆EN < 2.0 and it contains a metal, it is ionic, otherwise it is polar covalent

if 2.0 < ∆EN then the substance is ionic

CaF2 (calcium fluoride) has a ∆EN of 2.98.. so, it is definitely ionic

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