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The concentration of the reactants decreases.

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Cristobal Kuhlman

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2y ago
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11y ago

Enzymes catalyse the reaction, which basically means they are what makes the substance react. If you have less enzymes, then you have less collisions between the enzymes and the substrate, so less enzyme substrate complexes are formed, and so the reaction is slower. Remember enzymes don't get used up!

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11y ago

As the reaction progresses the concentration of the reactants decreases, this generally decreases the rate of reaction. the effect can be obscured if the reaction is exothermic when the increase in temperature compensates for the reduction in concentration.

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11y ago

There are formulae to explain this. But today let's use an analogy. In a barn filled with hundreds of men and women that are randomly distributed a line dance caller shouts "men, hold hands with the first woman you see!" At first, the boys and girls pair up quickly. (reaction rate is fast) But as more and more pair up, those still looking have to look harder and further to find a free partner. The first 30 pairs find each other quickly. The next 15 take a bit longer. The next couple a bit longer. But those last couple of men and women in a crowd of hundred might take quite a while to pair up.

It's the same for molecules except instead of hundreds, we are talking hundreds of billions. Now, there is an exception. Suppose that that same barn were filled with 1000 men and only 100 women. When the dance caller made his announcement the girls would all pair up very quickly since there are so many men to choose from. And then the rest of the men are just out of luck.

Same for molecules. If one reagent is in extreme excess, very little slowing in the reaction rate is detectable (there can still be some but very slight). So slight in fact, that it is really negligible.

If you want the formulas... flag this as not detailed enough and I will come back and write in the actual math.

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Q: What is the reason for the decrease of rate of reaction decrease after decrease in enzyme concentration?
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